In-situ hydrogenation of model compounds and raw bio-oil over Ni/CMK-3 catalyst
文献类型：期刊论文
| 作者 | Xu, Ying1,2,3 ; Li, Yanbin1; Wang, Congwei1,2,3; Wang, Chenguang1,2,3; Ma, Longlong1,2,3; Wang, Tiejun1,2,3; Zhang, Xinghua1,2,3; Zhang, Qi1,2,3
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| 刊名 | FUEL PROCESSING TECHNOLOGY
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| 出版日期 | 2017-06-15 |
| 卷号 | 161页码:226-231 |
| 关键词 | Bio-oil In-situ Hydrogenation Model Compounds Ni-base Catalyst Cmk-3 |
| DOI | 10.1016/j.fuproc.2016.08.018 |
| 文献子类 | Article |
| 英文摘要 | Ni/CMK-3 catalyst, the mesoporous carbon material loading Ni activity, was prepared and used in the in-situ hydrogenation of mixed model compounds (including acetone, acetic acid, furfural, o-cresol, ethanediol and water) of bio-oil (MCB) and actual bio-oil in this paper. The effects of hydrogen donors, solvents and the dosages of catalyst were all investigated in the in-situ hydrogenation process. The results showed that the hydrogen donor of methanol, ethanol and formic acid could all provide hydrogen for the in-situ hydrogenation but the product distributions of bio-oils were different after in-situ hydrogenation. Using alcohols as hydrogen donors, esterification reaction happened between the hydrogen donors and acetic acid. The formic acid could promote the phenols conversion but the conversion of acetic acid was restrained. When the radio of water and methanol was 10:3 and 10:5, most of ketones and aldehydes in the raw bio-oil converted to alcohols and the conversion of acids and phenols was beyond 50%. The contents of alcohols and esters in raw bio-oil increased from 18.52% to 51.14% and 48.21%. (C) 2016 Elsevier B.V. All rights reserved. |
| WOS关键词 | FAST PYROLYSIS ; PHENOLIC-COMPOUNDS ; NI CATALYST ; HYDRODEOXYGENATION ; ESTERIFICATION ; CONVERSION ; CARBON ; HYDROCARBONS ; ALCOHOLS ; QUALITY |
| 语种 | 英语 |
| WOS记录号 | WOS:000401047600027 |
| 资助机构 | Natural Science Foundation of China(51476178) ; Science and Technology Plan Key Project in Guangdong Province of China(2014A010106019) ; Youth Innovation Promotion Association CAS |
| 源URL | [http://ir.giec.ac.cn/handle/344007/14130]  |
| 专题 | 中国科学院广州能源研究所 |
| 作者单位 | 1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Guangdong, Peoples R China 2.Chinese Acad Sci, Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China 3.Guangdong Prov Key Lab New & Renewable Energy Res, Guangzhou 510640, Guangdong, Peoples R China |
| 推荐引用方式 GB/T 7714 | Xu, Ying,Li, Yanbin,Wang, Congwei,et al. In-situ hydrogenation of model compounds and raw bio-oil over Ni/CMK-3 catalyst[J]. FUEL PROCESSING TECHNOLOGY,2017,161:226-231. |
| APA | Xu, Ying.,Li, Yanbin.,Wang, Congwei.,Wang, Chenguang.,Ma, Longlong.,...&Zhang, Qi.(2017).In-situ hydrogenation of model compounds and raw bio-oil over Ni/CMK-3 catalyst.FUEL PROCESSING TECHNOLOGY,161,226-231. |
| MLA | Xu, Ying,et al."In-situ hydrogenation of model compounds and raw bio-oil over Ni/CMK-3 catalyst".FUEL PROCESSING TECHNOLOGY 161(2017):226-231. |
入库方式： OAI收割
来源：广州能源研究所
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