A ternary composite oxides S2O82-/ZrO2-TiO2SiO2 as an efficient solid super acid catalyst for depolymerization of lignin
文献类型：期刊论文
| 作者 | Wang, Huizhen1; Li, Wenzhi1; Wang, Jindong1; Chang, Hou-min2; Jameel, Hasan2; Zhang, Qi3 ; Li, Song2; Jin, Lele1
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| 刊名 | RSC ADVANCES
 |
| 出版日期 | 2017 |
| 卷号 | 7期号:79页码:50027-50034 |
| DOI | 10.1039/c7ra09489b |
| 文献子类 | Article |
| 英文摘要 | The solid, super, acid catalyst S2O82-/ZrO2-TiO2-SiO2, which has both a strong Bronsted acid and Lewis acid, was prepared and applied in lignin depolymerization. The results indicate that S2O82-/ZrO2-TiO2SiO2 is an effective catalyst for lignin depolymerisation since the liquid product was almost completely dissolved in ethyl acetate, indicating that it was comprised of mostly oligomeric lignin degradation products. The effect of hydrogenation co-catalysts (Pd/C, Pt/C and Ru/C, Rh/C) were also studied and found to improve the yield of aromatic compounds and the petroleum ether soluble fraction, which are mostly monomeric and dimeric products. The resulting yields of aromatic compounds and petroleum ether soluble products were 14.8% and 46%, respectively, when S2O82-/ZrO2-TiO2-SiO2 and Pt/C mixed catalyst was used at 310 degrees C for 24 hours. These results show that the use of a combination Bronsted and Lewis acid catalyst in combination with a hydrogenation catalyst (S2O82-/ZrO2-TiO2-SiO2 together with a noble metal catalyst) opens a practical route for efficient lignin depolymerization. |
| WOS关键词 | KRAFT LIGNIN ; LEWIS ; CHEMICALS ; TRANSFORMATION ; LIQUEFACTION ; DEGRADATION ; CONVERSION ; CELLULOSE ; CLEAVAGE ; BIOMASS |
| 语种 | 英语 |
| WOS记录号 | WOS:000413944200026 |
| 资助机构 | Program of National Natural Science Foundation of China(51676178) ; National Key Technology R&D Program of China(2015BAD15B06) ; Science and Technological Fund of Anhui Province for Outstanding Youth(1508085J01) ; international technology cooperation plan of Anhui(1503062030) |
| 源URL | [http://ir.giec.ac.cn/handle/344007/15861]  |
| 专题 | 中国科学院广州能源研究所 |
| 作者单位 | 1.Univ Sci & Technol China, Lab Basic Res Biomass Convers & Utilizat, Hefei 230026, Anhui, Peoples R China 2.North Carolina State Univ, Dept Forest Biomat, Raleigh, NC 27695 USA 3.Chinese Acad Sci, Guangzhou Inst Energy Convers, CAS Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Huizhen,Li, Wenzhi,Wang, Jindong,et al. A ternary composite oxides S2O82-/ZrO2-TiO2SiO2 as an efficient solid super acid catalyst for depolymerization of lignin[J]. RSC ADVANCES,2017,7(79):50027-50034. |
| APA | Wang, Huizhen.,Li, Wenzhi.,Wang, Jindong.,Chang, Hou-min.,Jameel, Hasan.,...&Jin, Lele.(2017).A ternary composite oxides S2O82-/ZrO2-TiO2SiO2 as an efficient solid super acid catalyst for depolymerization of lignin.RSC ADVANCES,7(79),50027-50034. |
| MLA | Wang, Huizhen,et al."A ternary composite oxides S2O82-/ZrO2-TiO2SiO2 as an efficient solid super acid catalyst for depolymerization of lignin".RSC ADVANCES 7.79(2017):50027-50034. |
入库方式： OAI收割
来源：广州能源研究所
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