Production of liquid fuel intermediates from furfural via aldol condensation over Lewis acid zeolite catalysts
文献类型：期刊论文
| 作者 | Su, Mingxue1; Li, Wenzhi1; Zhang, Tingwei1; Xin, HaoSheng2; Li, Song3; Fan, Wei4; Ma, Longlong
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| 刊名 | CATALYSIS SCIENCE & TECHNOLOGY
 |
| 出版日期 | 2017-08-21 |
| 卷号 | 7期号:16页码:3555-3561 |
| DOI | 10.1039/c7cy01028a |
| 文献子类 | Article |
| 英文摘要 | Aldol condensation reactions between furfural and acetone can be used to produce liquid fuel intermediates. It was found that tin-containing zeolites with MFI (Sn-MFI) and BEA* (Sn-Beta) framework structures are effective for C-C bond formation via the aldol condensation reactions between furfural and acetone. Aldol condensation between furfural and acetone produced two main products, 4-(2-furyl)-3-buten-2-one (FAc) and 1,5-di-2-furanyl-1,4-pentadien-3-one (F2Ac). Although both these catalysts were active for the aldol condensation reactions, different selectivities to aldol products were observed over Sn-MFI and Sn-Beta. FAc and F2Ac were formed over the Sn-Beta catalyst with selectivities to FAc of 40% and F2Ac of 22%, respectively. In contrast, only FAc was produced over Sn-MFI. The variation in selectivity is likely due to different pore geometries of Sn-Beta and Sn-MFI, suggesting that Sn-MFI exhibits shape selectivity for aldol condensation between furfural and acetone. In addition, it was found that the addition of water to the reaction system can also affect the product selectivity, leading to the aldol product exclusively being FAc over Sn-Beta. |
| WOS关键词 | DROP-IN BIOFUELS ; RANGE ALKANES ; CONVERSION ; ACETONE ; BASE ; FORMALDEHYDE ; KETONES ; DIESEL ; WATER ; JET |
| 语种 | 英语 |
| WOS记录号 | WOS:000407636600016 |
| 资助机构 | National Natural Science Foundation of China(51536009) ; National Key Technology R&D Program of China(2015BAD15B06) ; Science and Technological Fund of Anhui Province for Outstanding Youth(1508085J01) ; International Technology Cooperation Plan of Anhui(1503062030) |
| 源URL | [http://ir.giec.ac.cn/handle/344007/16285]  |
| 专题 | 中国科学院广州能源研究所 |
| 作者单位 | 1.Univ Sci & Technol China, Dept Thermal Sci & Energy Engn, Lab Basic Res Biomass Convers & Utilizat, Hefei 230026, Peoples R China 2.Anhui Jianzhu Univ, Inst Mat & Chem Engn, Hefei 230022, Anhui, Peoples R China 3.Chinese Acad Sci, Guangzhou Inst Energy Convers, CAS Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China 4.Univ Massachusetts Amherst, Dept Chem Engn, 686 N Pleasant St, Amherst, MA 01003 USA |
| 推荐引用方式 GB/T 7714 | Su, Mingxue,Li, Wenzhi,Zhang, Tingwei,et al. Production of liquid fuel intermediates from furfural via aldol condensation over Lewis acid zeolite catalysts[J]. CATALYSIS SCIENCE & TECHNOLOGY,2017,7(16):3555-3561. |
| APA | Su, Mingxue.,Li, Wenzhi.,Zhang, Tingwei.,Xin, HaoSheng.,Li, Song.,...&Ma, Longlong.(2017).Production of liquid fuel intermediates from furfural via aldol condensation over Lewis acid zeolite catalysts.CATALYSIS SCIENCE & TECHNOLOGY,7(16),3555-3561. |
| MLA | Su, Mingxue,et al."Production of liquid fuel intermediates from furfural via aldol condensation over Lewis acid zeolite catalysts".CATALYSIS SCIENCE & TECHNOLOGY 7.16(2017):3555-3561. |
入库方式： OAI收割
来源：广州能源研究所
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