HF(v’=3) forward scattering in the F+H2 reaction: Shape resonance and slow-down mechanism
文献类型:会议论文
作者 | Wang XA(王兴安) ; Dong WR(董文锐) ; Qiu MH(邱明辉) ; Ren ZF(任泽峰) ; Che L(车丽) ; Dai DX(戴东旭) ; Wang XY(王秀岩) ; Yang XM(杨学明) ; Sun ZG(孙志刚) ; Fu BN(傅碧娜) ; Li SR(李仕仁) ; Xu X(徐昕) ; Zhang DH(张东辉) |
出版日期 | 2009-06-01 |
会议名称 | XIII International Symposium on Molecular Physics |
会议日期 | 2009-6-1 |
会议地点 | 中国 |
页码 | 68/1 |
通讯作者 | 杨学明 |
中文摘要 | We present our recent experimental and theoretical result on the HF(V’=3) forward scattering in the F+H2 reaction, which is a long standing and intriguing issue. With crossed molecular beam experiments and accurate quantum dynamics calculations, we reveals that the forward scattering in the reaction channel is not caused by Feshbach or dynamical resonances as in the F+H2->HF(v’=2)+H reaction. It is caused predominantly by the slow-down mechanism over the centrifugal barrier in the exit channel, with some small contribution from the shape resonance mechanism in a very small collision energy regime slightly above the HF(v’=3) threshold. |
会议主办者 | 中国科学院大连化学物理研究所 |
学科主题 | 物理化学 |
语种 | 中文 |
源URL | [http://159.226.238.44/handle/321008/113960] ![]() |
专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
推荐引用方式 GB/T 7714 | Wang XA,Dong WR,Qiu MH,et al. HF(v’=3) forward scattering in the F+H2 reaction: Shape resonance and slow-down mechanism[C]. 见:XIII International Symposium on Molecular Physics. 中国. 2009-6-1. |
入库方式: OAI收割
来源:大连化学物理研究所
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