Speciation of antimony and arsenic in the soils and plants in an old antimony mine
文献类型:SCI/SSCI论文
作者 | Wei C. Y.; Ge, Z. F.; Chu, W. S.; Feng, R. W. |
发表日期 | 2015 |
关键词 | HPLC-ICP-MS XANES Methylation Soils Plants plasma-mass spectrometry hplc-icp-ms pteris-vittata contaminated soils natural-waters chromatography mobility environment sb extracts |
英文摘要 | The speciation changes of antimony (Sb) in soil-plant system are largely unknown as compared with those of arsenic (As). In this study, indigenous plants and associated soils were sampled at the Xikuangshan Sb mine (XKS), China. The Sb in the soils (441-1472 mg/kg) were far greater than As (32-354 mg/kg), and the Sb and As availabilities in the soils, were 5.5% and 3.9% in average, respectively. HPLC-ICP-MS revealed the presence of four species of Sb in the soils and plants, including Sb-III, Sb-V,TMSb and UnkSb (unknown). The use of ?CANES revealed that the UnkSb consisted of inorganic Sb in the form of Sb-V. Inorganic Sb were prevalent in the soil and plant samples at the eight sites, whereas TMSb was observed in only a few of the rhizosphere soils, and, in plants at a few of the sites, primarily in the leaves and to a lesser extent in the stems. Arsenic was detected in the soils primarily as inorganic forms, while, DMA was detected in high proportions in all of the plant tissues at all of the sites. The methylation of Sb was far less than that of As in the indigenous plants at XKS. The results suggest that As and Sb differ in transformation characteristics in the soil plant system in XKS. (C) 2014 Elsevier B.V. All rights reserved. |
出处 | Environmental and Experimental Botany |
卷 | 109 |
页 | 31-39 |
语种 | 英语 |
ISSN号 | 0098-8472 |
DOI标识 | 10.1016/j.envexpbot.2014.08.002 |
源URL | [http://ir.igsnrr.ac.cn/handle/311030/43580] ![]() |
专题 | 地理科学与资源研究所_历年回溯文献 |
推荐引用方式 GB/T 7714 | Wei C. Y.,Ge, Z. F.,Chu, W. S.,et al. Speciation of antimony and arsenic in the soils and plants in an old antimony mine. 2015. |
入库方式: OAI收割
来源:地理科学与资源研究所
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