Solution Enthalpy of Ionic Liquid [C5mim][Gly] by SAM
文献类型：会议论文
| 作者 | Fang DW(房大维) ; Zang SL(臧树良) ; UrsWelz-Biermann |
| 出版日期 | 2010-09-07 |
| 会议名称 | 2nd asia pacific conference on ionic liquids and green processes |
| 会议日期 | 2010-9-07 |
| 会议地点 | 中国 |
| 页码 | 177/2 |
| 通讯作者 | 臧树良 ; urs welz-biermann |
| 中文摘要 | this paper synthesize the ionic liquids including 1-pentyl-3-methylimidazolium glycine([c5mim][gly]). the molar enthalpies of solution, solhm(wc), of [c5mim][gly] with various amount of water and with various molalities were measured by the solution-reaction isoperibol calorimeter at (298.15±0.01)k. according to archer’s method, the standard molar enthalpis of solution of [c5mim][gly] with a known amounts of water, solh0m(wc), were obtained. in order to eliminate the effect of the small amount of water in [c5mim][gly] a linear fitting of solh0m(wc) against water content was carried out so that a good straight line was obtained and the intercept was the standard molar enthalpy of solution, solh0m (pure il[c5mim][gly]) = -51.59 kj•mol-1. using glasser’ theory of lattice energy, the hydration enthalpy of anion of glycine was estimated. |
| 会议主办者 | 中国科学院大连化学物理研究所 |
| 学科主题 | 物理化学 |
| 语种 | 中文 |
| 源URL | [http://159.226.238.44/handle/321008/114268]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 推荐引用方式 GB/T 7714 | Fang DW,Zang SL,UrsWelz-Biermann. Solution Enthalpy of Ionic Liquid [C5mim][Gly] by SAM[C]. 见:2nd asia pacific conference on ionic liquids and green processes. 中国. 2010-9-07. |
入库方式： OAI收割
来源：大连化学物理研究所
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