中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Thermophysical characterization of [C6py][NTf2]

文献类型:会议论文

作者Liu QS(刘青山) ; Li PP(李佩佩) ; Li ZP(李长平) ; UrsWelz-Biermann
出版日期2010-09-07
会议名称2nd asia pacific conference on ionic liquids and green processes
会议日期2010-9-07
会议地点中国
页码270/2
通讯作者urs welz-biermann ; 李长平
中文摘要ionic liquid (il) n-hexylpyridinium bis(trifluoromethylsulfonyl)imide ([c6py][ntf2]) was synthesized by ion exchange method. the density and surface tension of air- and water- stable hydrophobic il [c6py][ntf2] were measured and the recorded temperature was in a range of t = (283.15 – 338.15) k. the viscosity was measured in the range of t = (298.15 – 338.15) k. the conductivity was measured in the range of t = (283.15 – 338.15) k. the physicochemical properties of the il were estimated in terms of empirical and semi-empirical equations, as well as the interstice model theory at 298.15 k. the electrochemical stability of the il was determinated by cyclic voltammetry. the structure of the il was characterized by ft-ir spectroscopy. the melting temperature is 3.2 ̊c and the glass transition temperature is -76.5 ̊c according to the differential scanning calorimetry (dsc). there are two exothermic peaks for [c6py][ntf2] at -41.5 ̊c and -26.5 ̊c, which indicate [c6py][ntf2] has two crystal-forms.
会议主办者中国科学院大连化学物理研究所
学科主题物理化学
语种中文
源URL[http://159.226.238.44/handle/321008/114276]  
专题大连化学物理研究所_中国科学院大连化学物理研究所
推荐引用方式
GB/T 7714
Liu QS,Li PP,Li ZP,et al. Thermophysical characterization of [C6py][NTf2][C]. 见:2nd asia pacific conference on ionic liquids and green processes. 中国. 2010-9-07.

入库方式: OAI收割

来源:大连化学物理研究所

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