Insight into the phase evolution of iron phosphate catalyst during the oxidative bromination of methane
文献类型：会议论文
| 作者 | Lin RH(林荣和) ; Ding YJ(丁云杰) ; Gong LF(龚磊峰) ; Chen WM(陈维苗) ; Yan L(严丽) ; Lv Y(吕元) |
| 出版日期 | 2010-07-18 |
| 会议名称 | sixth tokyo conference on advanced catalytic science and technology & fifth asia pacific congress on catalysis |
| 会议日期 | 2010-7-18 |
| 会议地点 | 日本 |
| 页码 | 118/2 |
| 通讯作者 | 丁云杰 |
| 中文摘要 | fepo4/sio2,as an inexpensive and widely used material, was firstly employed for the oxidative bromination of methane, which showed effective and stable performance at 570℃, namely, 49% methane conversion and 95% total selectivity for ch3br/co(ch3br:co ≈1)were obtained on a single pass. the products could be directly used as a feedstock for the manufacture of acetic acid. 57fe mossbauer spectroscopic studies revealed that the fepo4 components of the fresh catalyst transformed quickly into stable active species during the induction period, and the active components of the stable catalyst have been found to consist of near-equimolar α-fe3(p2o7)2 and fe2p2o7. |
| 会议主办者 | catalysis society of japan |
| 学科主题 | 物理化学 |
| 语种 | 中文 |
| 源URL | [http://159.226.238.44/handle/321008/114504]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 推荐引用方式 GB/T 7714 | Lin RH,Ding YJ,Gong LF,et al. Insight into the phase evolution of iron phosphate catalyst during the oxidative bromination of methane[C]. 见:sixth tokyo conference on advanced catalytic science and technology & fifth asia pacific congress on catalysis. 日本. 2010-7-18. |
入库方式： OAI收割
来源：大连化学物理研究所
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