A porous Bronsted superacid as an efficient and durable solid catalyst
文献类型：期刊论文
| 作者 | Xiao, Feng-Shou4; Ma, Shengqian1; Meng, Xiangju4; Zheng, Anmin2; Sun, Yinyong2; Aguila, Briana1; Yi, Xianfeng2; Leng, Kunyue3; Hu, Kewei4; Sun, Qi4 |
| 刊名 | JOURNAL OF MATERIALS CHEMISTRY A
 |
| 出版日期 | 2018-10-14 |
| 卷号 | 6期号:38页码:18712-18719 |
| ISSN号 | 2050-7488 |
| DOI | 10.1039/c8ta06516k |
| 英文摘要 | The development of catalysts able to assist industrial chemical transformations is a topic of high importance. In view of the versatile catalytic capabilities of acid catalysts, extensive research efforts are being made to develop porous superacid materials with a high density of accessible active sites to replace molecular acid catalysts. Herein, we report the rational development of a porous Bronsted superacid by combining important elements that target high strength acidity into one material, as demonstrated by grafting the sulfonic acid group onto a highly fluorinated porous framework, where the acid strength and stability are greatly enhanced by an electron-withdrawing environment provided by the polymer backbone, reminiscent of that seen in Nafion (R) resin. In addition, the densely arranged acid groups that are confined in the three-dimensional nanospace facilitate the transfer of hydrons, thereby further increasing the acidity. By virtue of the pore structure and strong acidity, this system exhibits excellent performance for a wide range of reactions, far outperforming commercial acid resins under repeated batch and flow reaction conditions. Our findings demonstrate how this synthetic approach may instruct the future design of heterogeneous acid catalysts with advantageous reaction capabilities and stability. |
| WOS关键词 | CONJUGATED MICROPOROUS POLYMERS ; ACID CATALYST ; ORGANIC POLYMERS ; GREEN ; NMR ; ESTERIFICATION ; THRESHOLD ; ACYLATION ; STRENGTH ; SILICAS |
| 资助项目 | National Natural Science Foundation of China[21720102001] ; National Natural Science Foundation of China[21333009] ; National Natural Science Foundation of China[21422306] |
| WOS研究方向 | Chemistry ; Energy & Fuels ; Materials Science |
| 语种 | 英语 |
| 出版者 | ROYAL SOC CHEMISTRY |
| WOS记录号 | WOS:000451380800043 |
| 资助机构 | National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China |
| 源URL | [http://ir.wipm.ac.cn/handle/112942/13517]  |
| 专题 | 中国科学院武汉物理与数学研究所 |
| 通讯作者 | Xiao, Feng-Shou; Sun, Qi |
| 作者单位 | 1.Univ S Florida, Dept Chem, 4202 E Fowler Ave, Tampa, FL 33620 USA 2.Chinese Acad Sci, State Key Lab Magnet Resonance & Atom & Mol Phys, Wuhan Inst Phys & Math, Wuhan 430071, Hubei, Peoples R China 3.Harbin Inst Technol, Sch Chem Engn & Technol, Harbin 150001, Heilongjiang, Peoples R China 4.Zhejiang Univ, Dept Chem, Key Lab Appl Chem Zhejiang Prov, Hangzhou 310028, Zhejiang, Peoples R China |
| 推荐引用方式 GB/T 7714 | Xiao, Feng-Shou,Ma, Shengqian,Meng, Xiangju,et al. A porous Bronsted superacid as an efficient and durable solid catalyst[J]. JOURNAL OF MATERIALS CHEMISTRY A,2018,6(38):18712-18719. |
| APA | Xiao, Feng-Shou.,Ma, Shengqian.,Meng, Xiangju.,Zheng, Anmin.,Sun, Yinyong.,...&Sun, Qi.(2018).A porous Bronsted superacid as an efficient and durable solid catalyst.JOURNAL OF MATERIALS CHEMISTRY A,6(38),18712-18719. |
| MLA | Xiao, Feng-Shou,et al."A porous Bronsted superacid as an efficient and durable solid catalyst".JOURNAL OF MATERIALS CHEMISTRY A 6.38(2018):18712-18719. |
入库方式： OAI收割
来源：武汉物理与数学研究所
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