A non-destructive optical color space sensing system to quantify elemental and organic carbon in atmospheric particulate matter on Teflon and quartz filters
文献类型:期刊论文
作者 | Khuzestani, Reza Bashiri; Schauer, James J.; Wei, Yongjie; Zhang, Yang; Zhang, Yuanxun |
刊名 | ATMOSPHERIC ENVIRONMENT
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出版日期 | 2017 |
卷号 | 149期号:0页码:84-94 |
关键词 | Organic Carbon Elemental Carbon Cie-lab Optical Color Space System Model Uncertainty Teflon Filters |
英文摘要 | Optical color space sensing proved to be a valuable method in particle characterization since it provides a non-destructive, fast, and cost-efficient way to estimate organic and elemental carbon (OC, EC) in atmospheric particulate matter. Here we expand and validate the previous work with the measurement of the CIE-Lab optical color space system and development of a multi-parameter reference calibration model to estimate EC/OC collected on Teflon and quartz filters. Analysis of approximately 500 Teflon and quartz filter samples demonstrated that the described method could be a robust way to estimate EC and OC loadings on the filters. The results showed that the correlation coefficients between predicted and measured loadings for the model-estimated EC and OC were 0.951 (CV (RMSE) = 15.1%) and 0.908 (CV (RMSE) = 20.7%) on Teflon filters and 0.948 (CV (RMSE) = 17.4%) and 0.895 (CV (RMSE) = 21.1%) on quartz filters respectively. The model cross-validation also provided good agreement between the predicted EC and OC loadings on Teflon and quartz filters and the NIOSH thermal-optical method. It was also found that the mixing state of the chemical composition and sources of OC could interfere the absorption and scattering of light, which results in a model estimation uncertainty that should be evaluated within the model estimations. The non-destructive and low analytical cost of the method, when applied to Teflon filters that are used for mass measurement are a cost effective means for estimating EC and OC exposures and concentrations in health studies and large-scale monitoring campaigns. (C) 2016 Elsevier Ltd. All rights reserved. |
源URL | [http://ir.rcees.ac.cn/handle/311016/39235] ![]() |
专题 | 生态环境研究中心_环境化学与生态毒理学国家重点实验室 |
推荐引用方式 GB/T 7714 | Khuzestani, Reza Bashiri,Schauer, James J.,Wei, Yongjie,et al. A non-destructive optical color space sensing system to quantify elemental and organic carbon in atmospheric particulate matter on Teflon and quartz filters[J]. ATMOSPHERIC ENVIRONMENT,2017,149(0):84-94. |
APA | Khuzestani, Reza Bashiri,Schauer, James J.,Wei, Yongjie,Zhang, Yang,&Zhang, Yuanxun.(2017).A non-destructive optical color space sensing system to quantify elemental and organic carbon in atmospheric particulate matter on Teflon and quartz filters.ATMOSPHERIC ENVIRONMENT,149(0),84-94. |
MLA | Khuzestani, Reza Bashiri,et al."A non-destructive optical color space sensing system to quantify elemental and organic carbon in atmospheric particulate matter on Teflon and quartz filters".ATMOSPHERIC ENVIRONMENT 149.0(2017):84-94. |
入库方式: OAI收割
来源:生态环境研究中心
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