Reduced graphene oxide-NH2 modified low pressure nanofiltration composite hollow fiber membranes with improved water flux and antifouling capabilities
文献类型:期刊论文
作者 | Li, Xipeng; Zhao, Changwei; Yang, Mei; Yang, Bin; Hou, Deyin; Wang, Tao |
刊名 | APPLIED SURFACE SCIENCE
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出版日期 | 2017-10-15 |
卷号 | 419期号:0页码:418-428 |
关键词 | Reduced Graphene Oxide-nh2 Interfacial Polymerization Nanofiltration Composite Hollow Fiber Membrane Low Operating Pressure Antifouling Property |
英文摘要 | Reduced graphene oxide-NH2 (R-GO-NH2), a kind of amino graphene oxide, was embedded into the polyamide (PA) layer of nanofiltration (NF) composite hollow fiber membranes via interfacial polymerization to enhance the permeate flux and antifouling properties of NF membranes under low pressure conditions. In addition, it could mitigate the poor compatibility issue between graphene oxide materials and PA layer. To evaluate the influence of R-GO-NH2 on the performance of the NF composite hollow fiber membrane, SEM, AFM, FTIR, XPS and Zeta potentials were used to characterize the membranes. The results indicated that the compatibility and interactions between R-GO-NH2 and PA layer were enhanced, which was mainly due to the polymerization reaction between amino groups of R-GO-NH2 and acyl chloride groups of TMC. Therefore, salts rejection of the current membranes was improved significantly, and the modified membranes with 50 mg/L R-GO-NH2 demonstrated highest performance in terms of the rejections, which were 26.9%, 98.5%, 98.1%, and 96.1%, for NaCl, Na2SO4, MgSO4, and CaCl2 respectively. It was found that with the R-GO-NH2 contents rasing from 0 to 50 mg/L, pure water flux increased from 30.44 +/- 1.71 to 38.57 +/- 2.01 L/(m(2).h) at 2 bar. What's more, the membrane demonstrated improved antifouling properties. (C) 2017 Elsevier B.V. All rights reserved. |
源URL | [http://ir.rcees.ac.cn/handle/311016/39554] ![]() |
专题 | 生态环境研究中心_环境水质学国家重点实验室 |
推荐引用方式 GB/T 7714 | Li, Xipeng,Zhao, Changwei,Yang, Mei,et al. Reduced graphene oxide-NH2 modified low pressure nanofiltration composite hollow fiber membranes with improved water flux and antifouling capabilities[J]. APPLIED SURFACE SCIENCE,2017,419(0):418-428. |
APA | Li, Xipeng,Zhao, Changwei,Yang, Mei,Yang, Bin,Hou, Deyin,&Wang, Tao.(2017).Reduced graphene oxide-NH2 modified low pressure nanofiltration composite hollow fiber membranes with improved water flux and antifouling capabilities.APPLIED SURFACE SCIENCE,419(0),418-428. |
MLA | Li, Xipeng,et al."Reduced graphene oxide-NH2 modified low pressure nanofiltration composite hollow fiber membranes with improved water flux and antifouling capabilities".APPLIED SURFACE SCIENCE 419.0(2017):418-428. |
入库方式: OAI收割
来源:生态环境研究中心
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