中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Residue analysis of acephate and its metabolite methamidophos in open field and greenhouse pakchoi (Brassica campestris L.) by gas chromatography-tandem mass spectrometry

文献类型:期刊论文

作者Tao Chuanjiang; Li Dahui; Zhang Xinzhong; Chen Shanshan; Fu Lijuan; Piao Xiuying; Shi Jie; Jiang Hui; Li Chongjiu; Li Jianzhong
刊名ENVIRONMENTAL MONITORING AND ASSESSMENT
出版日期2010-06
卷号165期号:3页码:685-692
关键词Acephate Gc Gc-ms/ms Methamidophos Residues
英文摘要To analysze the dynamic degradation and final residues of acephate and its metabolite methamidophos, field-experiments with pakchoi (Brassica campestris L.) in open field and greenhouse were carried out in Beijing, China in 2004 and 2005. The degradation dynamics and final residues were determined by gas chromatography (GC) equipped with a pulsed flame photometric detector and GC coupled to mass spectrometry (MS)/MS after acephate was applied on open field and green house pakchoi (B. campestris L.). The dynamic degradation results showed that the half-lives of acephate and methamidophos in open field pakchoi were 1.36 days with dynamic degradation equation C (t) = 133.01e (-aEuro parts per thousand 0.5107t) , and 2.86 days with C (t) = 6.5753e (-aEuro parts per thousand 0.2422t) , respectively. While the half-lives of acephate and methamidophos in the greenhouse were 1.07 days with C (t) = 59.134e (-aEuro parts per thousand 0.4353t) and 0.79 days with C (t) = 0.2703e (-aEuro parts per thousand 0.2595t) , respectively. The final residue analysis demonstrated that > 50% of total methamidophos were resulted from the degradation of acephate 7 and 18 days after it was applied on the greenhouse pakchoi, respectively. While in the open-field pakchoi, > 90% of total methamidophos was found to be the metabolite of acephate.
WOS记录号WOS:000277371000058
源URL[http://ir.rcees.ac.cn/handle/311016/21348]  
专题生态环境研究中心_中国科学院环境生物技术重点实验室
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Tao Chuanjiang,Li Dahui,Zhang Xinzhong,et al. Residue analysis of acephate and its metabolite methamidophos in open field and greenhouse pakchoi (Brassica campestris L.) by gas chromatography-tandem mass spectrometry[J]. ENVIRONMENTAL MONITORING AND ASSESSMENT,2010,165(3):685-692.
APA Tao Chuanjiang.,Li Dahui.,Zhang Xinzhong.,Chen Shanshan.,Fu Lijuan.,...&Li Jianzhong.(2010).Residue analysis of acephate and its metabolite methamidophos in open field and greenhouse pakchoi (Brassica campestris L.) by gas chromatography-tandem mass spectrometry.ENVIRONMENTAL MONITORING AND ASSESSMENT,165(3),685-692.
MLA Tao Chuanjiang,et al."Residue analysis of acephate and its metabolite methamidophos in open field and greenhouse pakchoi (Brassica campestris L.) by gas chromatography-tandem mass spectrometry".ENVIRONMENTAL MONITORING AND ASSESSMENT 165.3(2010):685-692.

入库方式: OAI收割

来源:生态环境研究中心

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