Regio- and stereoselective anomeric esterification of glucopyranose 1,2-diols and a facile preparation of 2-O-acetylated glucopyranosyl trichloroacetimidates from the corresponding 1,2-diols
文献类型：期刊论文
| 作者 | Zhang, Jianjun; Liang, Xiaomei; Wang, Daoquan; Kong, Fanzuo |
| 刊名 | CARBOHYDRATE RESEARCH
 |
| 出版日期 | 2007-05-07 |
| 卷号 | 342期号:6页码:797-805 |
| 关键词 | Esterification Acetyl Chloride Allyl Chloroformate Ethyl Chloroformate Glucopyranose 1 2-diols |
| 英文摘要 | A highly regio- and stereoselective anomeric esterification of 3-O-allyl (or benzyl, or benzoyl)-4,6-O-isopropylidene-alpha,beta-D-glucopyranose with acetyl chloride, or allyl chloroformate, or ethyl chloroformate gave the corresponding 2-OH, 1-beta-acetates or -carbonates in excellent yields. The 2-OH, 1-beta-acetates were readily converted to the corresponding 2-O-acetylated glucopyranosyl trichloroacetimidates by reaction with trichloroacetonitrile via base promoted acetyl migration, while the 2-OH, 1-beta-carbonates were good glycosyl acceptors for the synthesis of (1 -> 2)-linked oligosaccharides. (c) 2007 Elsevier Ltd. All rights reserved. |
| WOS记录号 | WOS:000245396700003 |
| 源URL | [http://ir.rcees.ac.cn/handle/311016/22672]  |
| 专题 | 生态环境研究中心_中国科学院环境生物技术重点实验室 |
| 推荐引用方式 GB/T 7714 | Zhang, Jianjun,Liang, Xiaomei,Wang, Daoquan,et al. Regio- and stereoselective anomeric esterification of glucopyranose 1,2-diols and a facile preparation of 2-O-acetylated glucopyranosyl trichloroacetimidates from the corresponding 1,2-diols[J]. CARBOHYDRATE RESEARCH,2007,342(6):797-805. |
| APA | Zhang, Jianjun,Liang, Xiaomei,Wang, Daoquan,&Kong, Fanzuo.(2007).Regio- and stereoselective anomeric esterification of glucopyranose 1,2-diols and a facile preparation of 2-O-acetylated glucopyranosyl trichloroacetimidates from the corresponding 1,2-diols.CARBOHYDRATE RESEARCH,342(6),797-805. |
| MLA | Zhang, Jianjun,et al."Regio- and stereoselective anomeric esterification of glucopyranose 1,2-diols and a facile preparation of 2-O-acetylated glucopyranosyl trichloroacetimidates from the corresponding 1,2-diols".CARBOHYDRATE RESEARCH 342.6(2007):797-805. |
入库方式： OAI收割
来源：生态环境研究中心
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