First synthesis of beta-D-Galf-(1 -> 3)-D-Galp - the repeating unit of the backbone structure of the O-antigenic polysaccharide present in the lipopolysaccharide (LPS) of the genus Klebsiella
文献类型：期刊论文
| 作者 | Wang, HR; Zhang, GH; Ning, J |
| 刊名 | CARBOHYDRATE RESEARCH
 |
| 出版日期 | 2003 |
| 卷号 | 338期号:10页码:1033-1037 |
| 关键词 | Oligosaccharides Galactofuranose Synthesis |
| DOI | 10.1016/S0008-6215(03)00076-4 |
| 英文摘要 | b-D-Galactofuranosyl-(1 --> 3)-D-galactopyranose (1), the repeating unit of the backbone structure of the O-antigenic polysaccharide present in the lipopolysaccharide (LPS) of the genus Klebsiella, has been efficiently synthesized using 1,2:5,6-di-O-isopropylidine-alpha-D-galactofuranose (3) as the glycosyl acceptor and 2,3,5,6-tetra-0-benzoyl-p-D-galactofuranosyl trichloroacetimidate (6) as the glycosyl donor with TMSOTf as catalyst by the well-known Schmidt glycosylation method. The preparation of 3 was improved by increasing the ratio of DMF to acetone and employing a solid-supported catalyst. (C) 2003 Elsevier Science Ltd. All rights reserved. |
| WOS研究方向 | Biochemistry & Molecular Biology ; Chemistry |
| WOS记录号 | WOS:000182642600002 |
| 源URL | [http://ir.rcees.ac.cn/handle/311016/23820]  |
| 专题 | 生态环境研究中心_中国科学院环境生物技术重点实验室 |
| 推荐引用方式 GB/T 7714 | Wang, HR,Zhang, GH,Ning, J. First synthesis of beta-D-Galf-(1 -> 3)-D-Galp - the repeating unit of the backbone structure of the O-antigenic polysaccharide present in the lipopolysaccharide (LPS) of the genus Klebsiella[J]. CARBOHYDRATE RESEARCH,2003,338(10):1033-1037. |
| APA | Wang, HR,Zhang, GH,&Ning, J.(2003).First synthesis of beta-D-Galf-(1 -> 3)-D-Galp - the repeating unit of the backbone structure of the O-antigenic polysaccharide present in the lipopolysaccharide (LPS) of the genus Klebsiella.CARBOHYDRATE RESEARCH,338(10),1033-1037. |
| MLA | Wang, HR,et al."First synthesis of beta-D-Galf-(1 -> 3)-D-Galp - the repeating unit of the backbone structure of the O-antigenic polysaccharide present in the lipopolysaccharide (LPS) of the genus Klebsiella".CARBOHYDRATE RESEARCH 338.10(2003):1033-1037. |
入库方式： OAI收割
来源：生态环境研究中心
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