Synthesis of beta-D-Glcp NAc-(1 -> 3)-alpha-L-Rhap -(1 -> 2)-[beta-L-Xylp-(1 -> 4]-alpha-L-Rhap-(1 -> 3)-alpha-L-Rhap, the repeating unit of the O-antigen produced by Pseudomonas solanacearum ICMP 7942
文献类型：期刊论文
| 作者 | Zhang, JJ; Kong, FZ |
| 刊名 | CARBOHYDRATE RESEARCH
 |
| 出版日期 | 2003 |
| 卷号 | 338期号:1页码:19-27 |
| 关键词 | Oligosaccharide Rhamnose Glucosamine |
| DOI | 10.1016/S0008-6215(02)00358-0 |
| 英文摘要 | An efficient synthesis Of beta-D-GlcpNAc-(1 --> 3)-alpha-L-Rhap-(1 --> 2)-[beta-L-Xylp-(1 --> 4)]-alpha-L-Rhap-(1 --> 3)-alpha-L-Rhap, the repeating unit of the O-antigen produced by Pseudomonas solanacearum ICMP 7942 and its isomer beta-D-Glcp NAc-(1 --> 3)-alpha-L-Rhap-(1 --> 4)-[beta-L-Xylp-(1 --> 2)] -alpha-L-Rhap-(1 --> 3)-alpha-L-Rhap was achieved via sequential assembly of the building blocks, allyl 2,3-0-isopropylidene-OC-L-rhamnopyranoside (2), allyl 3,4-O-isopropylidene-alpha-L-rhamnopyranoside (3), allyl 2,4-di-O-benzoyl-alpha-L-rhamnopyranoside (6), 3,4,6-tri-O-acetyl-2-deoxy-2-phthalimido-beta-D-glucopyranosyl trichloroacetimidate (7), and 2,3,4-tri-O-benzoyl-beta-L-xylopyranosyl trichloroacetimidate (12). The process was carried out in a regio- and stereoselective manner using glycosyl trichloroacetimidates as donors and unprotected or partially protected rhamnopyranosides as acceptors in the presence of a catalytic amount of trimethylsilyl trifluoromethanesulfonate (TMSOTf). (C) 2002 Elsevier Science Ltd. All rights reserved. |
| WOS研究方向 | Biochemistry & Molecular Biology ; Chemistry |
| WOS记录号 | WOS:000180405000003 |
| 源URL | [http://ir.rcees.ac.cn/handle/311016/23835]  |
| 专题 | 生态环境研究中心_中国科学院环境生物技术重点实验室 |
| 推荐引用方式 GB/T 7714 | Zhang, JJ,Kong, FZ. Synthesis of beta-D-Glcp NAc-(1 -> 3)-alpha-L-Rhap -(1 -> 2)-[beta-L-Xylp-(1 -> 4]-alpha-L-Rhap-(1 -> 3)-alpha-L-Rhap, the repeating unit of the O-antigen produced by Pseudomonas solanacearum ICMP 7942[J]. CARBOHYDRATE RESEARCH,2003,338(1):19-27. |
| APA | Zhang, JJ,&Kong, FZ.(2003).Synthesis of beta-D-Glcp NAc-(1 -> 3)-alpha-L-Rhap -(1 -> 2)-[beta-L-Xylp-(1 -> 4]-alpha-L-Rhap-(1 -> 3)-alpha-L-Rhap, the repeating unit of the O-antigen produced by Pseudomonas solanacearum ICMP 7942.CARBOHYDRATE RESEARCH,338(1),19-27. |
| MLA | Zhang, JJ,et al."Synthesis of beta-D-Glcp NAc-(1 -> 3)-alpha-L-Rhap -(1 -> 2)-[beta-L-Xylp-(1 -> 4]-alpha-L-Rhap-(1 -> 3)-alpha-L-Rhap, the repeating unit of the O-antigen produced by Pseudomonas solanacearum ICMP 7942".CARBOHYDRATE RESEARCH 338.1(2003):19-27. |
入库方式： OAI收割
来源：生态环境研究中心
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。