Facile and effective synthesis of glucopyranosyl oligosacchardes with alternative (1 -> 3)-alpha- and -beta-linkages in the presence of C-2 ester capable of neighboring group participation
文献类型:期刊论文
作者 | Zeng, Y; Ning, J; Kong, FZ |
刊名 | CHINESE JOURNAL OF CHEMISTRY
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出版日期 | 2002 |
卷号 | 20期号:11页码:1142-1144 |
关键词 | Oligosaccharide Remote Control Regio- And Stereoselective Synthesis |
英文摘要 | Coupling of acetylated alpha-(1-->3)-linked glucobiosyl trichloroacetimidate with acetylated alpha-(1-->3)-linked glucobioside acceptor gave an alpha-linked tetrasaccharide, while coupling of acetylated beta-(1-->3)-linked glumbiosyl trichloroacetimidate with acetylated beta-(1-->3)-linked glucobioside acceptor gave an alpha-linked tetrasaccharide in spite of the C-2 neighboring group participation. Two hexasaccharides with alternative (1-->3)-alpha-and -beta-linkges were synthesized by these reactions via remote control exerted by the glycosylation bond in either donor or acceptor. |
WOS研究方向 | Chemistry |
WOS记录号 | WOS:000179210800003 |
源URL | [http://ir.rcees.ac.cn/handle/311016/23965] ![]() |
专题 | 生态环境研究中心_中国科学院环境生物技术重点实验室 |
推荐引用方式 GB/T 7714 | Zeng, Y,Ning, J,Kong, FZ. Facile and effective synthesis of glucopyranosyl oligosacchardes with alternative (1 -> 3)-alpha- and -beta-linkages in the presence of C-2 ester capable of neighboring group participation[J]. CHINESE JOURNAL OF CHEMISTRY,2002,20(11):1142-1144. |
APA | Zeng, Y,Ning, J,&Kong, FZ.(2002).Facile and effective synthesis of glucopyranosyl oligosacchardes with alternative (1 -> 3)-alpha- and -beta-linkages in the presence of C-2 ester capable of neighboring group participation.CHINESE JOURNAL OF CHEMISTRY,20(11),1142-1144. |
MLA | Zeng, Y,et al."Facile and effective synthesis of glucopyranosyl oligosacchardes with alternative (1 -> 3)-alpha- and -beta-linkages in the presence of C-2 ester capable of neighboring group participation".CHINESE JOURNAL OF CHEMISTRY 20.11(2002):1142-1144. |
入库方式: OAI收割
来源:生态环境研究中心
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