Preparation of polyelectrolyte multilayer membranes by dynamic layer-by-layer process for pervaporation separation of alcohol/water mixtures
文献类型：期刊论文
| 作者 | Wang, Zhan; Liu, Zhongzhou; Ji, Shulan; Gu, Weiliang; Zhang, Guojun; Peng, Yuelian |
| 刊名 | JOURNAL OF MEMBRANE SCIENCE
 |
| 出版日期 | 2006 |
| 卷号 | 280期号:2015-01-02页码:727-733 |
| 关键词 | Polyelectrolyte Multilayer Membranes Dynamic Layer-by-layer Process Polyacrylic Acid (Paa) Polyethyleneimine (Pei) Pervaporation Water/alcohol Mixture |
| 英文摘要 | In the past decades, the layer-by-layer (LBL) adsorption of oppositely charged polyelectrolytes has proven to be a promising method for the preparation of polyelectrolyte multilayer membranes. However, to obtain a good separation capability, LBL adsorption involved relatively long periods because 50-60 bilayers were normally required. The aim of this study was to develop such a new method that would allow simplification of the LBL procedure. LBL adsorption was proposed to proceed under a dynamic condition to prepare polyelectrolyte multilayer membranes. The polyacrylic acid (PAA) and polyethyleneimine (PEI) were alternatively deposited on polyethersulfone (PES) ultrafiltration support membrane under a pressure of 0.1 MPa. The polyelectrolyte multilayer membranes prepared by dynamic LBL process were compared with those prepared by the static LBL process for the pervaporation separation of water-ethanol mixture. The results suggested that a relatively high separation factor could be obtained with only four composite bilayers by using dynamic LBL process. The preparative conditions including bilayer number, filtration time of the first PAA layer, reaction time, ratio between polayanion and polycation concentrations, PAA molecular weight and salt addition were investigated. The pervaporation conditions such as feed temperature and water concentration in the feed were also evaluated. Under the temperature of 40 degrees C, the separation factor and the permeate flux of the polyelectrolyte multilayer membranes were about 1207 and 140 g/(m(2)h), respectively. (c) 2006 Published by Elsevier B.V. |
| WOS记录号 | WOS:000239472900084 |
| 源URL | [http://ir.rcees.ac.cn/handle/311016/23041]  |
| 专题 | 生态环境研究中心_水污染控制实验室 |
| 推荐引用方式 GB/T 7714 | Wang, Zhan,Liu, Zhongzhou,Ji, Shulan,et al. Preparation of polyelectrolyte multilayer membranes by dynamic layer-by-layer process for pervaporation separation of alcohol/water mixtures[J]. JOURNAL OF MEMBRANE SCIENCE,2006,280(2015-01-02):727-733. |
| APA | Wang, Zhan,Liu, Zhongzhou,Ji, Shulan,Gu, Weiliang,Zhang, Guojun,&Peng, Yuelian.(2006).Preparation of polyelectrolyte multilayer membranes by dynamic layer-by-layer process for pervaporation separation of alcohol/water mixtures.JOURNAL OF MEMBRANE SCIENCE,280(2015-01-02),727-733. |
| MLA | Wang, Zhan,et al."Preparation of polyelectrolyte multilayer membranes by dynamic layer-by-layer process for pervaporation separation of alcohol/water mixtures".JOURNAL OF MEMBRANE SCIENCE 280.2015-01-02(2006):727-733. |
入库方式： OAI收割
来源：生态环境研究中心
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