中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Risk assessment of heavy metal contaminated soil in the vicinity of a lead/zinc mine

文献类型:期刊论文

作者Naidu, R; Li, J; Xie, ZM; Zhu, YG
刊名JOURNAL OF ENVIRONMENTAL SCIENCES-CHINA
出版日期2005
卷号17期号:6页码:881-885
关键词Fractionation Heavy Metal Mining Tailings Risk Assessment Soil Pollution
英文摘要Heavy metal contamination of soils through anthropogenic activities is a widespread and serious problem confronting scientists and regulators throughout the world. In this study we investigated the distribution, chemical species and availability of lead, zinc, cadmium and copper in nine surface(0 to 20 cm) soils from near an abandoned lead/zinc mine tailings located in Shaoxing, Zhejiang, China. Total heavy metal contents ranged from 5271 to 16369 mg/kg for Pb, 387 to 1221 mg/kg for Zn, 3.0 to 9.3 mg/kg for Cd and 65 to 206 mg/kg for Cu. In general, all heavy metals exceeded China National Standards for Soil Environmental Quality of Heavy Metals by a factor of 3-65 times. Comparison of the heavy metal concentrations( Pb, Zn, Cd and Cu) with clay content revealed a strongly significant relationship while significant relationship( P < 0.001) was also obtained between Cd + Zn and Pb + Cu. Solid phase speciation of the soils using Tessier procedure showed that the heavy metals were distributed in the order: residual >> organically complexed-Fe-Mn oxides occluded > carbonate bound > exchangeable > water soluble. In the organic matter fraction, the ratio of Pb(29.1%) to its total concentration in the soils was higher than those of Zn(4.70%), Cd(3.16%) and Cu(9.50%). The percentages of the water soluble and the exchangeable fractions of Pb(1.80%) and Cd(2.74%) were markedly greater than those of Zn(0.10%) and Cu(0.15%), suggesting that Pb and Cd are relatively more mobile and hence more toxic in the contaminated soils. Strongly significant relationships between H-2 O-Pb, H-2 O-Zn and H-2 O-Cu, strong positive correlations between H-2 O-Pb, H-2 O-Zn, H-2 O-Cu and organic matter in soil were found. The content of H-2 O-Pb, H-2 O-Zn, H, O-Cu was negatively correlated with pH values. The similar negative relationships between pH values and exchangeable heavy metals were also recorded. It is suggested that increasing soil pH or liming the soil could decrease bioavailability of heavy metals in the soil.
学科主题Environmental Sciences & Ecology
WOS研究方向Environmental Sciences & Ecology
WOS记录号WOS:000233402200001
源URL[http://ir.rcees.ac.cn/handle/311016/23354]  
专题生态环境研究中心_土壤环境科学实验室
推荐引用方式
GB/T 7714
Naidu, R,Li, J,Xie, ZM,et al. Risk assessment of heavy metal contaminated soil in the vicinity of a lead/zinc mine[J]. JOURNAL OF ENVIRONMENTAL SCIENCES-CHINA,2005,17(6):881-885.
APA Naidu, R,Li, J,Xie, ZM,&Zhu, YG.(2005).Risk assessment of heavy metal contaminated soil in the vicinity of a lead/zinc mine.JOURNAL OF ENVIRONMENTAL SCIENCES-CHINA,17(6),881-885.
MLA Naidu, R,et al."Risk assessment of heavy metal contaminated soil in the vicinity of a lead/zinc mine".JOURNAL OF ENVIRONMENTAL SCIENCES-CHINA 17.6(2005):881-885.

入库方式: OAI收割

来源:生态环境研究中心

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