Influence of pretreatment conditions on low-temperature CO oxidation over Au/MOx/Al2O3 catalysts
文献类型:期刊论文
作者 | Shi, XC; Wang, DH; Hao, ZP; Cheng, DY; Hu, C |
刊名 | JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL
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出版日期 | 2003 |
卷号 | 200期号:1页码:229-238 |
关键词 | Gold Catalyst Co Oxidation Composite Oxide Support Pretreatment Conditions Gold Nanoparticle |
DOI | 10.1016/S1381-1169(03)00007-4 |
英文摘要 | Composite oxide MOx/Al2O3 supported gold catalysts for low-temperature CO oxidation were prepared and investigated. The presence of transition metal oxide was proved to be beneficial to the improvement of catalytic performance of Au/Al2O3 catalysts for low-temperature CO oxidation. Furthermore, the influence of various pretreatment conditions on Au/MOx/Al2O3 catalysts was studied carefully. The image of TEM showed that gold catalyst with small gold particles only in the form of a fine dispersion exhibited highly catalytic activity. The XPS, Fourier transform infrared (FTIR) spectroscopy characterization results of Au/FeOx/Al2O3 catalyst showed that gold catalysts having partially oxidized gold species have the best catalytic performance. One possible pathway for CO oxidation on Au/FeOx/Al2O3 catalyst is that the CO adsorbed on gold particles reacts with adsorbed oxygen, which is possible to occur on oxygen vacancies on the support or at the metal-support interface. (C) 2003 Elsevier Science B.V. All rights reserved. |
WOS研究方向 | Chemistry |
WOS记录号 | WOS:000183168200024 |
源URL | [http://ir.rcees.ac.cn/handle/311016/23791] ![]() |
专题 | 生态环境研究中心_水污染控制实验室 |
推荐引用方式 GB/T 7714 | Shi, XC,Wang, DH,Hao, ZP,et al. Influence of pretreatment conditions on low-temperature CO oxidation over Au/MOx/Al2O3 catalysts[J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL,2003,200(1):229-238. |
APA | Shi, XC,Wang, DH,Hao, ZP,Cheng, DY,&Hu, C.(2003).Influence of pretreatment conditions on low-temperature CO oxidation over Au/MOx/Al2O3 catalysts.JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL,200(1),229-238. |
MLA | Shi, XC,et al."Influence of pretreatment conditions on low-temperature CO oxidation over Au/MOx/Al2O3 catalysts".JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL 200.1(2003):229-238. |
入库方式: OAI收割
来源:生态环境研究中心
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