Direct synthesis of dimethyl carbonate and propylene glycol using potassium bicarbonate as catalyst in supercritical CO2
文献类型：期刊论文
| 作者 | Cang, Yu; Zhang, Rui; Wen, Yicun; Fan, Bin; Guo, Xuhong; Liu, Lixiao; Zhang, Jianchao |
| 刊名 | POLISH JOURNAL OF CHEMICAL TECHNOLOGY
 |
| 出版日期 | 2015 |
| 卷号 | 17期号:1页码:62-65 |
| 关键词 | Direct Synthesis Dimethyl Carbonate Carbon Dioxide Potassium Bicarbonate Supercritical Fluids |
| 英文摘要 | The improved one-pot synthesis of dimethyl carbonate and propylene glycol from propylene oxide, supercritical carbon dioxide, and methanol with potassium bicarbonate as the catalyst has been reported in this paper. As far as we know, it is the first time to use potassium bicarbonate only as the catalyst in the production process which is simple and cheap. Satisfactory conversion rate of propylene oxide and yield of the products could be achieved at the optimized conditions with quite a small amount of by-products. Our new method offers an attractive choice for the production of dimethyl carbonate in large-scale industry efficiently and environmental friendly. |
| WOS研究方向 | Chemistry, Applied ; Engineering, Chemical |
| WOS记录号 | WOS:000351850800010 |
| 源URL | [http://ir.rcees.ac.cn/handle/311016/32876]  |
| 专题 | 生态环境研究中心_水污染控制实验室 |
| 推荐引用方式 GB/T 7714 | Cang, Yu,Zhang, Rui,Wen, Yicun,et al. Direct synthesis of dimethyl carbonate and propylene glycol using potassium bicarbonate as catalyst in supercritical CO2[J]. POLISH JOURNAL OF CHEMICAL TECHNOLOGY,2015,17(1):62-65. |
| APA | Cang, Yu.,Zhang, Rui.,Wen, Yicun.,Fan, Bin.,Guo, Xuhong.,...&Zhang, Jianchao.(2015).Direct synthesis of dimethyl carbonate and propylene glycol using potassium bicarbonate as catalyst in supercritical CO2.POLISH JOURNAL OF CHEMICAL TECHNOLOGY,17(1),62-65. |
| MLA | Cang, Yu,et al."Direct synthesis of dimethyl carbonate and propylene glycol using potassium bicarbonate as catalyst in supercritical CO2".POLISH JOURNAL OF CHEMICAL TECHNOLOGY 17.1(2015):62-65. |
入库方式： OAI收割
来源：生态环境研究中心
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