中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Atomic layer reversal on CeO2 (100) surface

文献类型:期刊论文

作者Yu, Rong; Huang, Jinglu; Yu, Yunbo; Zhu, Jing
刊名SCIENCE CHINA-MATERIALS
出版日期2017-09-01
卷号60期号:9页码:903-908
关键词Surface Structure Ceria Atomic Layer Reversal Aberration-corrected Tem First-principles Calculations
英文摘要The structure and properties of CeO2 surfaces have been intensively studied due to their importance in a lot of surface-related applications. Since most of surface techniques probe the structure information inside the outermost surface plane, the subsurface structure information has been elusive in many studies. Using the profile imaging with aberration-corrected transmission electron microscopy, the structure information in both the outermost layer and the sublayers of the CeO2 (100) surface has been obtained. In addition to the normal structures that have been reported before, where the surface is Ce-or O-terminated, a metastable surface has been discovered. In the new structure, there is an atomic layer reversal between the outermost layer and the sublayer, giving a structure with O as the outermost layer for the stoichiometry of normal Ce-terminated surface. The charge redistribution for the polarity compensation has also been changed relative to the normal surface.
源URL[http://ir.rcees.ac.cn/handle/311016/39186]  
专题生态环境研究中心_大气污染控制中心
推荐引用方式
GB/T 7714
Yu, Rong,Huang, Jinglu,Yu, Yunbo,et al. Atomic layer reversal on CeO2 (100) surface[J]. SCIENCE CHINA-MATERIALS,2017,60(9):903-908.
APA Yu, Rong,Huang, Jinglu,Yu, Yunbo,&Zhu, Jing.(2017).Atomic layer reversal on CeO2 (100) surface.SCIENCE CHINA-MATERIALS,60(9),903-908.
MLA Yu, Rong,et al."Atomic layer reversal on CeO2 (100) surface".SCIENCE CHINA-MATERIALS 60.9(2017):903-908.

入库方式: OAI收割

来源:生态环境研究中心

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