Efficient Nitrate Reduction in a Fluidized Electrochemical Reactor Promoted by Pd-Sn/AC Particles
文献类型：期刊论文
| 作者 | Lan, Huachun; Liu, Xiaobin; Liu, Huijuan; Liu, Ruiping; Hu, Chengzhi; Qu, Jiuhui |
| 刊名 | CATALYSIS LETTERS
 |
| 出版日期 | 2016-01 |
| 卷号 | 146期号:1页码:91-99 |
| 关键词 | Nitrate Electrochemical Reduction Pd-sn/ac Enhancement |
| DOI | 10.1007/s10562-015-1615-3 |
| 英文摘要 | Pd-Sn modified activated carbon (Pd-Sn/AC) was prepared by impregnation of Pd and Sn salts onto AC followed by heat treatment. Based on scanning electron microscopy, transmission electron microscopy, and X-ray diffraction analysis, Pd-Sn alloy was highly dispersed on the surface of AC with a atomic ratio of about 4.21. A double electrolysis cell was established and separated via a proton-exchange membrane. In the cathodic cell compartment, the as-prepared Pd-Sn/AC was used as particle electrodes where electrolytic reduction of nitrate was performed. A batch mode study showed that at an applied current of 30 mA with 7.5 g/L catalyst, over 90 % of the nitrate could be reduced in 80 min when the nitrate initial concentration was 24.6 mg/L. The electro-catalytic process of nitrate reduction could be satisfactorily described with a first-order kinetics model. With increasing applied current, the nitrate removal rate increased; whereas, the NH4+ concentration increased as well. The inhibition effect of coexisting anions and cations on nitrate reduction followed this order: Fe3+ > Mn2+ > Ca2+ > Na+ and Cl- < SO42- < HCO3-. [GRAPHICS] . |
| 源URL | [http://ir.rcees.ac.cn/handle/311016/36174]  |
| 专题 | 生态环境研究中心_中国科学院饮用水科学与技术重点实验室 |
| 推荐引用方式 GB/T 7714 | Lan, Huachun,Liu, Xiaobin,Liu, Huijuan,et al. Efficient Nitrate Reduction in a Fluidized Electrochemical Reactor Promoted by Pd-Sn/AC Particles[J]. CATALYSIS LETTERS,2016,146(1):91-99. |
| APA | Lan, Huachun,Liu, Xiaobin,Liu, Huijuan,Liu, Ruiping,Hu, Chengzhi,&Qu, Jiuhui.(2016).Efficient Nitrate Reduction in a Fluidized Electrochemical Reactor Promoted by Pd-Sn/AC Particles.CATALYSIS LETTERS,146(1),91-99. |
| MLA | Lan, Huachun,et al."Efficient Nitrate Reduction in a Fluidized Electrochemical Reactor Promoted by Pd-Sn/AC Particles".CATALYSIS LETTERS 146.1(2016):91-99. |
入库方式： OAI收割
来源：生态环境研究中心
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