中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Evolution behavior of oxide scales of TiAlCrN coatings at high temperature

文献类型:期刊论文

作者Hao Junying2; Yu Yuan1,2; Zhang Shuaituo1,2; Zhou Haibin1,2; Li Guojian3; Sui Xudong1,2,3; Wang Qiang3
刊名SURFACE & COATINGS TECHNOLOGY
出版日期2019-02
期号360页码:133-139
关键词Tialcrn Oxidation Resistance Oxide Scale Xps
DOI10.1016/j.surfcoat.2019.01.016
英文摘要

Coating oxidation performance is a major concern in modern machining and other high temperature applications. This study presents TiAICrN composite coatings with different Cr content prepared on a magnetron sputtering device. SEM, AFM and XRD were used to determine the structure of the coatings. It was found that the coatings show a solid solution of B1-NaCl face-centered cubic structure with [200] preferential orientation. As the Cr content increases, the particle size and roughness of the coating increase slightly, while the hardness of the coating decreases. Oxidation tests revealed that no significant oxidation occurs in all coatings below 800 degrees C. However, as the oxidation temperature increases to 1000 degrees C, the Ti0.32Al0.38Cr0.30N coating undergoes severe oxidation and the Ti0.17Al0.19Cr0.64N coating remains good. The oxide scale of the coatings after oxidation test is analysis by XPS depth profiling in details. XPS results revealed that the oxide scale of the Ti0.32Al0.38Cr0.30N coating changes from a dense Al rich oxide layer (800 degrees C) to a loose and discontinuous Ti-Al rich oxide layer (1000 degrees C), which is the main reason for its poor oxidation resistance. However, the Ti0.17Al0.19Cr0.64N coating shows a top loose Ti-Al rich oxide layer and a dense bottom Cr Al rich oxide layer. The presence of this dense and continuous Cr Al rich oxide layer can limit the rapid diffusion of Ti atoms to the surface while preventing the oxygen atoms from diffusing into the interior, which is the key to excellent oxidation resistance of the Ti0.17Al0.19Cr0.64N coatings.

语种英语
源URL[http://210.77.64.217/handle/362003/24991]  
专题兰州化学物理研究所_固体润滑国家重点实验室
兰州化学物理研究所_青岛研发中心/青岛市资源化学与新材料研究中心
通讯作者Sui Xudong
作者单位1.Qingdao Ctr Resource Chem & New Mat, Qingdao 266000, Peoples R China
2.State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, China
3.Northeastern Univ, Minist Educ, Key Lab Electromagnet Proc Mat, Shenyang 110004, Liaoning, Peoples R China
推荐引用方式
GB/T 7714
Hao Junying,Yu Yuan,Zhang Shuaituo,et al. Evolution behavior of oxide scales of TiAlCrN coatings at high temperature[J]. SURFACE & COATINGS TECHNOLOGY,2019(360):133-139.
APA Hao Junying.,Yu Yuan.,Zhang Shuaituo.,Zhou Haibin.,Li Guojian.,...&Wang Qiang.(2019).Evolution behavior of oxide scales of TiAlCrN coatings at high temperature.SURFACE & COATINGS TECHNOLOGY(360),133-139.
MLA Hao Junying,et al."Evolution behavior of oxide scales of TiAlCrN coatings at high temperature".SURFACE & COATINGS TECHNOLOGY .360(2019):133-139.

入库方式: OAI收割

来源:兰州化学物理研究所

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