中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Iron-doped nickel phosphide nanosheets in-situ grown on Ni sub-microwires as efficient electrocatalysts for oxygen evolution reaction

文献类型:期刊论文

作者Jiahui Chen; Yuming Li; Guoqing Sheng; Lu Xu; Huangqing Ye; Xian-Zhu Fu; Rong Sun; Ching-Ping Wong
刊名ChemCatChem
出版日期2018
文献子类期刊论文
英文摘要Tens of micrometers long metallic Ni sub-microwires with diameter around 200 nm are prepared by a chemical reduction method under a magnetic field. Fe-doped Ni2P nanosheets are then in situ grown on Ni sub-microwires by a simple wet-chemical reaction followed a subsequent low-temperature phosphorization process. The (Ni0.87Fe0.13)2P-Ni composite exhibits the highest catalytic activity toward OER in alkaline solution among all the as-prepared (Ni1-xFex)2P-Ni catalysts, delivering a current density of 10 mA cm-2 at an overpotential of only 257 mV and keeping high stability over a 10 h electrolysis. These exceptional activities are attributed to the unique structure combining metallic Ni sub-microwires as good electronic conductive substrate and in-situ grown Fe-doped Ni2P nanosheets. Specifically, Fe incorporation leads to strong electron interactions between Ni, Fe and P, fast reaction kinetics, small charge transfer resistance and large electrochemical surface area, which are responsible for the excellent catalytic performance.
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语种英语
源URL[http://ir.siat.ac.cn:8080/handle/172644/13620]  
专题深圳先进技术研究院_集成所
推荐引用方式
GB/T 7714
Jiahui Chen,Yuming Li,Guoqing Sheng,et al. Iron-doped nickel phosphide nanosheets in-situ grown on Ni sub-microwires as efficient electrocatalysts for oxygen evolution reaction[J]. ChemCatChem,2018.
APA Jiahui Chen.,Yuming Li.,Guoqing Sheng.,Lu Xu.,Huangqing Ye.,...&Ching-Ping Wong.(2018).Iron-doped nickel phosphide nanosheets in-situ grown on Ni sub-microwires as efficient electrocatalysts for oxygen evolution reaction.ChemCatChem.
MLA Jiahui Chen,et al."Iron-doped nickel phosphide nanosheets in-situ grown on Ni sub-microwires as efficient electrocatalysts for oxygen evolution reaction".ChemCatChem (2018).

入库方式: OAI收割

来源:深圳先进技术研究院

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