Hydrogen-Bonded Organic-Inorganic Hybrid Based on Hexachloroplatinate and Nitrogen Heterocyclic Cations: Their Synthesis, Characterization, Crystal Structures, and Antitumor Activities In Vitro
文献类型：期刊论文
| 作者 | Chen, Fuming; Zhao, Jin; Han, Yutong; Chen, Huaqing; Luo, Zhidong; Tian, Hao; Zhao, Yi; Ma, Aiqing; Zhu, Longguan |
| 刊名 | MOLECULES
 |
| 出版日期 | 2018 |
| 文献子类 | 期刊论文 |
| 英文摘要 | Three new crystal structures containing [PtCl6](2-), pyridinium and benzimidazole groups have been prepared: [PtCl6]center dot(H-bzm)(2)center dot 2(H2O) (1), [PtCl6]center dot(H-bipy)(2)center dot 2(H2O) (2), [PtCl6]center dot(H-dimethyl-ipy)(2)center dot 2(H2O) (3) [H-bzm: benzimidazole cation, H-bipy: 2,2'bipyridine cation, H-dimethyl-bipy: 4,4'-bimethyl-2,2'bipyridine cation]. All compounds have been fully characterized by elemental analyses, single-crystal X-ray analyses, IR spectra, TG analyses, and fluorescence studies. Single-crystal X-ray diffraction analysis suggests that the primary synthon contains N+-H center dot center dot center dot Cl- including ionic bonding and hydrogen bonding interactions. The dimensions are enhanced further by secondary O-H center dot center dot Cl and N-H center dot center dot O hydrogen bonding interactions between donor and acceptor atoms located at the periphery of these synthons. Moreover, coulombic attractions between the ions play an important role in reinforcing the structures of these complexes. In addition, antitumor activity against human lung adenocarcinoma cell line (A549) and human nasopharyngeal carcinoma cell line (CNE-2) was performed. These complexes all showed inhibition to the two cell lines, while complex 3 exhibited higher efficiency than complexes 1-2. |
| URL标识 | 查看原文 |
| 语种 | 英语 |
| 源URL | [http://ir.siat.ac.cn:8080/handle/172644/14602]  |
| 专题 | 深圳先进技术研究院_医药所 |
| 推荐引用方式 GB/T 7714 | Chen, Fuming,Zhao, Jin,Han, Yutong,et al. Hydrogen-Bonded Organic-Inorganic Hybrid Based on Hexachloroplatinate and Nitrogen Heterocyclic Cations: Their Synthesis, Characterization, Crystal Structures, and Antitumor Activities In Vitro[J]. MOLECULES,2018. |
| APA | Chen, Fuming.,Zhao, Jin.,Han, Yutong.,Chen, Huaqing.,Luo, Zhidong.,...&Zhu, Longguan.(2018).Hydrogen-Bonded Organic-Inorganic Hybrid Based on Hexachloroplatinate and Nitrogen Heterocyclic Cations: Their Synthesis, Characterization, Crystal Structures, and Antitumor Activities In Vitro.MOLECULES. |
| MLA | Chen, Fuming,et al."Hydrogen-Bonded Organic-Inorganic Hybrid Based on Hexachloroplatinate and Nitrogen Heterocyclic Cations: Their Synthesis, Characterization, Crystal Structures, and Antitumor Activities In Vitro".MOLECULES (2018). |
入库方式： OAI收割
来源：深圳先进技术研究院
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