AgBF4/[emim][BF4] supported ionic liquid membrane for carbon monoxide/nitrogen separation
文献类型：期刊论文
| 作者 | Feng, Shichao; Wu, Yuanyuan; Luo, Jianquan; Wan, Yinhua |
| 刊名 | JOURNAL OF ENERGY CHEMISTRY
 |
| 出版日期 | 2019-02-01 |
| 卷号 | 29页码:31-39 |
| 关键词 | Supported ionic liquid membranes [emim][BF4] AgBF4 Carbon monoxide separation |
| ISSN号 | 2095-4956 |
| DOI | 10.1016/j.jechem.2018.02.004 |
| 英文摘要 | In this paper, AgBF4/[emim][BF4] supported ionic liquid membranes (SILMs) were prepared successfully for CO/N-2 separation using nitrogen pressure immobilization procedures. The incorporation of AgBF4 could decrease membrane weight loss, improve the pressure-resistant ability, and keep the critical pressure (0.45 MPa) of the SILMs. The high viscosity and undissolved AgBF4 solids in membrane liquid would disturb gas molecular transport through membrane and give rise to the gas transport resistance. Therefore, the gas permeability decreased remarkably with increasing AgBF4 carrier content in the membrane. When the molar ratio of AgBF4 to [emim][BF4] increased from 0:1 to 0.3:1, the CO/N-2 selectivity of the SILMs showed a great increase from similar to 1 to similar to 9 at 20 degrees C and 0.4MPa, suggesting that AgBF4 was an effective carrier for CO facilitated transport. The permeabilities of N-2 and CO increased at higher transmembrane pressure, indicating that molecular transport would dominate the transport process at high pressure. The temperature-dependent gas permeability followed the Arrhenius equation. Moreover, the differences between the activation energies of CO and N-2 became larger after introducing AgBF4, resulting in more obvious decrease in the CO/N-2 selectivity at higher operating temperature. (C) 2018 Science Press and Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier By, and Science Press. All rights reserved. |
| WOS关键词 | BLEND MEMBRANES ; FACILITATED TRANSPORT ; COMPOSITE MEMBRANES ; GAS SOLUBILITY ; CO2 ; MONOXIDE ; AG+ |
| 资助项目 | National Natural Science Foundation of China[21406235] |
| WOS研究方向 | Chemistry ; Energy & Fuels ; Engineering |
| 语种 | 英语 |
| WOS记录号 | WOS:000451732100006 |
| 出版者 | ELSEVIER SCIENCE BV |
| 资助机构 | National Natural Science Foundation of China |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/27596]  |
| 专题 | 中国科学院过程工程研究所 |
| 通讯作者 | Wan, Yinhua |
| 作者单位 | Chinese Acad Sci, Inst Proc Engn, State Key Lab Biochem Engn, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Feng, Shichao,Wu, Yuanyuan,Luo, Jianquan,et al. AgBF4/[emim][BF4] supported ionic liquid membrane for carbon monoxide/nitrogen separation[J]. JOURNAL OF ENERGY CHEMISTRY,2019,29:31-39. |
| APA | Feng, Shichao,Wu, Yuanyuan,Luo, Jianquan,&Wan, Yinhua.(2019).AgBF4/[emim][BF4] supported ionic liquid membrane for carbon monoxide/nitrogen separation.JOURNAL OF ENERGY CHEMISTRY,29,31-39. |
| MLA | Feng, Shichao,et al."AgBF4/[emim][BF4] supported ionic liquid membrane for carbon monoxide/nitrogen separation".JOURNAL OF ENERGY CHEMISTRY 29(2019):31-39. |
入库方式： OAI收割
来源：过程工程研究所
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