Solvation effect of [BMIM]Cl/AlCl3 ionic liquid electrolyte
文献类型：期刊论文
| 作者 | Kang, Yanhong1,2; Chen, Shimou1; Wang, Qian1; Lang, Haiyan1; Jia, Chuqiao2; Zhang, Bo2 |
| 刊名 | IONICS
 |
| 出版日期 | 2019 |
| 卷号 | 25期号:1页码:163-169 |
| 关键词 | Ionic liquids Electrodeposition Aluminum Solvation effect |
| ISSN号 | 0947-7047 |
| DOI | 10.1007/s11581-018-2586-3 |
| 英文摘要 | Four kinds of solvents, methylene chloride (CH2Cl2), toluene (TOL), ethyl acetate (EtoAc), and dimethyl carbonate (DMC), were added into the 1-butyl-3-methylimidazolium chloroaluminate ionic liquid ([BMIM]Cl/AlCl3 IL) to improve the property of the IL-based electrolyte for aluminum (Al) electrolysis. Solvation effects of these solvents on the physical properties, electrochemical properties, and electroactive ion of the [BMIM]Cl/AlCl3 IL-based electrolyte were investigated. It was found that the viscosity of the IL electrolyte decreased after adding CH2Cl2 or TOL, and the conductivity increased while the change of the conductivity and the viscosity moved in the opposite direction with the addition of EtoAc or DMC. The UV-Vis spectra showed that the electroactive Al ion continued existence after adding CH2Cl2 or TOL, but there was solvation effect between TOL and BMIM+. On the other hand, both EtoAc and DMC had solvation effects with electroactive Al ion and BMIM+. The results illustrated that solvation effect was the key effect on the reduction of Al on the cathode, and further influenced the morphology of the Al deposits. In addition, the concentration polarization reduced and the efficiency of electrolysis improved after adding CH2Cl2 or TOL. Furthermore, bright Al coatings were obtained finally by adding CH2Cl2 into [BMIM]Cl/AlCl3 IL electrolyte (when the mole ratio of CH2Cl2 is around 66.7 similar to 75%). |
| WOS关键词 | ELECTRODEPOSITION ; ALUMINUM ; AL ; 1H-1,2,4-TRIAZOLE ; MORPHOLOGY ; ADDITIVES ; MIXTURES ; STEEL |
| 资助项目 | National Natural Science Foundation of China[21276257] ; National Natural Science Foundation of China[21210006] ; National Natural Science Foundation of China[51404230] ; Beijing Natural Science Foundation of China[2132054] ; National Key Technology Research and Development Program of the Ministry of Science and Technology of China[2012BAF03B01] ; Department of Education of Liaoning Province Science Foundation[L201602] |
| WOS研究方向 | Chemistry ; Electrochemistry ; Physics |
| 语种 | 英语 |
| WOS记录号 | WOS:000455254500018 |
| 出版者 | SPRINGER HEIDELBERG |
| 资助机构 | National Natural Science Foundation of China ; Beijing Natural Science Foundation of China ; National Key Technology Research and Development Program of the Ministry of Science and Technology of China ; Department of Education of Liaoning Province Science Foundation |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/27770]  |
| 专题 | 中国科学院过程工程研究所 |
| 通讯作者 | Kang, Yanhong; Chen, Shimou |
| 作者单位 | 1.Chinese Acad Sci, Beijing Key Lab Ion Liquids Clean Proc, Key Lab Green Proc & Engn, State Key Lab Multiphase Complex Syst,Inst Proc E, Beijing 100190, Peoples R China 2.Shenyang Normal Univ, Coll Chem & Chem Engn, Shenyang 110034, Liaoning, Peoples R China |
| 推荐引用方式 GB/T 7714 | Kang, Yanhong,Chen, Shimou,Wang, Qian,et al. Solvation effect of [BMIM]Cl/AlCl3 ionic liquid electrolyte[J]. IONICS,2019,25(1):163-169. |
| APA | Kang, Yanhong,Chen, Shimou,Wang, Qian,Lang, Haiyan,Jia, Chuqiao,&Zhang, Bo.(2019).Solvation effect of [BMIM]Cl/AlCl3 ionic liquid electrolyte.IONICS,25(1),163-169. |
| MLA | Kang, Yanhong,et al."Solvation effect of [BMIM]Cl/AlCl3 ionic liquid electrolyte".IONICS 25.1(2019):163-169. |
入库方式： OAI收割
来源：过程工程研究所
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