中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
A new solid-state electrolyte based on polymeric ionic liquid for high-performance supercapacitor

文献类型:期刊论文

作者Wen, Xinge1; Dong, Tao2; Liu, Ao2; Zheng, Shuohang2; Chen, Shimou2; Han, Yifan1; Zhang, Suojiang2
刊名IONICS
出版日期2019
卷号25期号:1页码:241-251
关键词Polymeric ionic liquid Solid-state electrolyte Supercapacitor High conductivity
ISSN号0947-7047
DOI10.1007/s11581-018-2582-7
英文摘要As a polymer host, one polymeric ionic liquid poly(methyl methacrylate-1-vinyl-3-ethyl-imidazolium bis(trifluoromethylsulfonyl) imide) (abbr. P(MMA-co-VEImTFSI)) was successfully synthesized and characterized. Four poly(vinylidene fluoride-co-hexafluoropropylene) (abbr. PVDF-HFP)-based polymer electrolytes were prepared by blending 0, 5,15, and 25wt% P(MMA-co-VEImTFSI). The electrochemical performances of the prepared electrolytes were studied carefully. The results revealed that increasing the polymeric ionic liquid content, the ionic conductivity of the polymer electrolytes could be enhanced and it obeyed the Arrhenius rule. The highest ionic conductivity of the polymer electrolytes was up to 2.09x10(-3)Scm(-1) at room temperature. The polymer with 25wt% polymeric ionic liquid showed an excellent electrochemical performance for supercapacitor electrolyte. After 2000 cycles, the retention of capacitance in P(MMA-co-VEImTFSI)-based polymer electrolyte was above 80%. It implied that the present P(MMA-co-VEImTFSI) polymeric ionic liquid was a decent component candidate in the high-performance polymer electrolytes.
WOS关键词GEL ELECTROLYTE ; CONDUCTIVITY ; MEMBRANES ; STRATEGY ; CATIONS ; PMMA
资助项目National Key R&D Program of China[2017YFB0102000] ; National Natural Science Foundation of China[91534109] ; National Natural Science Foundation of China[51561145020] ; Key Research Program of Frontier Sciences, CAS[QYZDY-SSW-JSC011] ; CAS/SAFEA International Partnership Program for Creative Research Teams[20140491518] ; Science and Technology Open Cooperation Project of Henan province[17210110019]
WOS研究方向Chemistry ; Electrochemistry ; Physics
语种英语
WOS记录号WOS:000455254500026
出版者SPRINGER HEIDELBERG
资助机构National Key R&D Program of China ; National Natural Science Foundation of China ; Key Research Program of Frontier Sciences, CAS ; CAS/SAFEA International Partnership Program for Creative Research Teams ; Science and Technology Open Cooperation Project of Henan province
源URL[http://ir.ipe.ac.cn/handle/122111/27812]  
专题中国科学院过程工程研究所
通讯作者Han, Yifan; Zhang, Suojiang
作者单位1.Zhengzhou Univ, Sch Chem Engn & Energy, Zhengzhou 450001, Henan, Peoples R China
2.Chinese Acad Sci, Beijing Key Lab Ion Liquids Clean Proc, CAS Key Lab Green Proc & Engn, State Key Lab Multiphase Complex Syst,Inst Proc E, Beijing 100190, Peoples R China
推荐引用方式
GB/T 7714
Wen, Xinge,Dong, Tao,Liu, Ao,et al. A new solid-state electrolyte based on polymeric ionic liquid for high-performance supercapacitor[J]. IONICS,2019,25(1):241-251.
APA Wen, Xinge.,Dong, Tao.,Liu, Ao.,Zheng, Shuohang.,Chen, Shimou.,...&Zhang, Suojiang.(2019).A new solid-state electrolyte based on polymeric ionic liquid for high-performance supercapacitor.IONICS,25(1),241-251.
MLA Wen, Xinge,et al."A new solid-state electrolyte based on polymeric ionic liquid for high-performance supercapacitor".IONICS 25.1(2019):241-251.

入库方式: OAI收割

来源:过程工程研究所

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