A new solid-state electrolyte based on polymeric ionic liquid for high-performance supercapacitor
文献类型:期刊论文
作者 | Wen, Xinge1; Dong, Tao2; Liu, Ao2; Zheng, Shuohang2; Chen, Shimou2; Han, Yifan1; Zhang, Suojiang2 |
刊名 | IONICS
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出版日期 | 2019 |
卷号 | 25期号:1页码:241-251 |
关键词 | Polymeric ionic liquid Solid-state electrolyte Supercapacitor High conductivity |
ISSN号 | 0947-7047 |
DOI | 10.1007/s11581-018-2582-7 |
英文摘要 | As a polymer host, one polymeric ionic liquid poly(methyl methacrylate-1-vinyl-3-ethyl-imidazolium bis(trifluoromethylsulfonyl) imide) (abbr. P(MMA-co-VEImTFSI)) was successfully synthesized and characterized. Four poly(vinylidene fluoride-co-hexafluoropropylene) (abbr. PVDF-HFP)-based polymer electrolytes were prepared by blending 0, 5,15, and 25wt% P(MMA-co-VEImTFSI). The electrochemical performances of the prepared electrolytes were studied carefully. The results revealed that increasing the polymeric ionic liquid content, the ionic conductivity of the polymer electrolytes could be enhanced and it obeyed the Arrhenius rule. The highest ionic conductivity of the polymer electrolytes was up to 2.09x10(-3)Scm(-1) at room temperature. The polymer with 25wt% polymeric ionic liquid showed an excellent electrochemical performance for supercapacitor electrolyte. After 2000 cycles, the retention of capacitance in P(MMA-co-VEImTFSI)-based polymer electrolyte was above 80%. It implied that the present P(MMA-co-VEImTFSI) polymeric ionic liquid was a decent component candidate in the high-performance polymer electrolytes. |
WOS关键词 | GEL ELECTROLYTE ; CONDUCTIVITY ; MEMBRANES ; STRATEGY ; CATIONS ; PMMA |
资助项目 | National Key R&D Program of China[2017YFB0102000] ; National Natural Science Foundation of China[91534109] ; National Natural Science Foundation of China[51561145020] ; Key Research Program of Frontier Sciences, CAS[QYZDY-SSW-JSC011] ; CAS/SAFEA International Partnership Program for Creative Research Teams[20140491518] ; Science and Technology Open Cooperation Project of Henan province[17210110019] |
WOS研究方向 | Chemistry ; Electrochemistry ; Physics |
语种 | 英语 |
WOS记录号 | WOS:000455254500026 |
出版者 | SPRINGER HEIDELBERG |
资助机构 | National Key R&D Program of China ; National Natural Science Foundation of China ; Key Research Program of Frontier Sciences, CAS ; CAS/SAFEA International Partnership Program for Creative Research Teams ; Science and Technology Open Cooperation Project of Henan province |
源URL | [http://ir.ipe.ac.cn/handle/122111/27812] ![]() |
专题 | 中国科学院过程工程研究所 |
通讯作者 | Han, Yifan; Zhang, Suojiang |
作者单位 | 1.Zhengzhou Univ, Sch Chem Engn & Energy, Zhengzhou 450001, Henan, Peoples R China 2.Chinese Acad Sci, Beijing Key Lab Ion Liquids Clean Proc, CAS Key Lab Green Proc & Engn, State Key Lab Multiphase Complex Syst,Inst Proc E, Beijing 100190, Peoples R China |
推荐引用方式 GB/T 7714 | Wen, Xinge,Dong, Tao,Liu, Ao,et al. A new solid-state electrolyte based on polymeric ionic liquid for high-performance supercapacitor[J]. IONICS,2019,25(1):241-251. |
APA | Wen, Xinge.,Dong, Tao.,Liu, Ao.,Zheng, Shuohang.,Chen, Shimou.,...&Zhang, Suojiang.(2019).A new solid-state electrolyte based on polymeric ionic liquid for high-performance supercapacitor.IONICS,25(1),241-251. |
MLA | Wen, Xinge,et al."A new solid-state electrolyte based on polymeric ionic liquid for high-performance supercapacitor".IONICS 25.1(2019):241-251. |
入库方式: OAI收割
来源:过程工程研究所
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