Synthesis of high purity ammonium alum crystallized from solutions containing impurities
文献类型：期刊论文
| 作者 | You, Shaowei1,3; Guo, Tao1,2; Liu, Pengfei1; Mao, Xiang3; Zhang, Yifei1; Zhang, Yi1 |
| 刊名 | JOURNAL OF CRYSTAL GROWTH
 |
| 出版日期 | 2019-02-01 |
| 卷号 | 507页码:168-174 |
| 关键词 | Purification Impurities Aluminum recovery Industrial crystallization Ammonium alum |
| ISSN号 | 0022-0248 |
| DOI | 10.1016/j.jcrysgro.2018.11.005 |
| 英文摘要 | Synthesis of high purity ammonium alum crystallized from solutions containing impurities was investigated. It was found that various parameters, including initial Al-2(SO4)(3) concentration, supersaturation, temperature and agitation, have a great effect on the purity of ammonium alum crystals. EDS analysis of crystals indicates that K+ ions were more easily included into ammonium alum crystals than other impurities. Impurities were removed more effectively by non-agitation crystallization than by agitation crystallization. In non-agitation crystallization, the content of K in crystals was drastically decreased and Na, Ca, Mg and Si were almost removed. Ammonium alum crystals with high purity were successfully synthesized by the method of non-agitation recrystallization. Distribution coefficient K-K was much greater than K-Na, which explained that K+ ion was more easily incorporated into ammonium alum crystals than Na+ ion. |
| WOS关键词 | COAL FLY-ASH ; EXTRACTING ALUMINA ; BATCH CRYSTALLIZATION ; NUCLEATION ; KINETICS ; RECOVERY ; SULFATE ; GROWTH ; IONS ; PURIFICATION |
| 资助项目 | National Natural Science Foundation of China[21276258] ; National Natural Science Foundation of China[51674233] ; National High Technology Research and Development Program of China[2011AA060701] ; Science and Technology Innovation Commission of Shenzhen[JCYJ20170302141241005] |
| WOS研究方向 | Crystallography ; Materials Science ; Physics |
| 语种 | 英语 |
| WOS记录号 | WOS:000455667500028 |
| 出版者 | ELSEVIER SCIENCE BV |
| 资助机构 | National Natural Science Foundation of China ; National High Technology Research and Development Program of China ; Science and Technology Innovation Commission of Shenzhen |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/27824]  |
| 专题 | 中国科学院过程工程研究所 |
| 通讯作者 | You, Shaowei; Zhang, Yifei |
| 作者单位 | 1.Chinese Acad Sci, Natl Engn Lab Hydrometallurg Cleaner Prod Technol, Key Lab Green Proc & Engn, Inst Proc Engn, Beijing 100190, Peoples R China 2.Shenzhen Univ, Coll Chem & Environm Engn, Dept Environm Engn, Shenzhen 518060, Peoples R China 3.Chinese Acad Sci, Tech Inst Phys & Chem, Beijing, Peoples R China |
| 推荐引用方式 GB/T 7714 | You, Shaowei,Guo, Tao,Liu, Pengfei,et al. Synthesis of high purity ammonium alum crystallized from solutions containing impurities[J]. JOURNAL OF CRYSTAL GROWTH,2019,507:168-174. |
| APA | You, Shaowei,Guo, Tao,Liu, Pengfei,Mao, Xiang,Zhang, Yifei,&Zhang, Yi.(2019).Synthesis of high purity ammonium alum crystallized from solutions containing impurities.JOURNAL OF CRYSTAL GROWTH,507,168-174. |
| MLA | You, Shaowei,et al."Synthesis of high purity ammonium alum crystallized from solutions containing impurities".JOURNAL OF CRYSTAL GROWTH 507(2019):168-174. |
入库方式： OAI收割
来源：过程工程研究所
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