An integrated high-throughput strategy enables the discovery of multifunctional ionic liquids for sustainable chemical processes
文献类型：期刊论文
| 作者 | Zhu, Anlian1; Li, Lingjun1; Zhang, Chi1; Shen, Yutan1; Tang, Mingjie1; Bai, Lili1; Du, Chunyan1; Zhang, Suojiang2; Wang, Jianji1 |
| 刊名 | GREEN CHEMISTRY
 |
| 出版日期 | 2019-01-21 |
| 卷号 | 21期号:2页码:307-313 |
| ISSN号 | 1463-9262 |
| DOI | 10.1039/c8gc03119c |
| 英文摘要 | Development of new chemical processes with simplified reaction systems and work-up procedures is a challenging task. Although ionic liquids are a class of potential multifunctional compounds to simplify traditional chemical processes, their rational design is difficult due to complex interactions. In this work, a proof-of-concept strategy has been proposed to achieve an integration of high-throughput preparation of ionic liquids and in situ screening of their reaction-promoting performance in 96-well plates. The integrated approach then enables a facile identification of optimal ionic liquids from a 400-ionic liquid candidate pool to act as the solvent, the catalyst and the separating assistant, simultaneously, for carbonylazide cycloaddition reactions. Merits of the ionic liquids-based processes have been demonstrated not only in the convenient and efficient synthesis of 1,2,3-triazolyl compounds but also in the discovery of a new reaction for the chemical post-modification of free peptides. |
| WOS关键词 | REGIOSELECTIVE SYNTHESIS ; CLICK CHEMISTRY ; IDENTIFICATION ; EFFICIENT ; LIGANDS ; CARBON |
| 资助项目 | National Natural Science Foundation of China[21373079] ; National Natural Science Foundation of China[21778015] ; Program for Science & Technology Innovation Talents in Universities of Henan Province[14HASTIT015] ; 111 Project[D17007] |
| WOS研究方向 | Chemistry ; Science & Technology - Other Topics |
| 语种 | 英语 |
| WOS记录号 | WOS:000457596200011 |
| 出版者 | ROYAL SOC CHEMISTRY |
| 资助机构 | National Natural Science Foundation of China ; Program for Science & Technology Innovation Talents in Universities of Henan Province ; 111 Project |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/27879]  |
| 专题 | 中国科学院过程工程研究所 |
| 通讯作者 | Li, Lingjun; Wang, Jianji |
| 作者单位 | 1.Henan Normal Univ, Collaborat Innovat Ctr Henan Prov Green Mfg Fine, Henan Key Lab Organ Funct Mol & Drug Innovat, Sch Chem & Chem Engn,Minist Educ,Key Lab Green Ch, Xinxiang 453007, Henan, Peoples R China 2.Chinese Acad Sci, CAS Key Lab Green Proc & Engn, Beijing Key Lab Ion Liquids Clean Proc, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhu, Anlian,Li, Lingjun,Zhang, Chi,et al. An integrated high-throughput strategy enables the discovery of multifunctional ionic liquids for sustainable chemical processes[J]. GREEN CHEMISTRY,2019,21(2):307-313. |
| APA | Zhu, Anlian.,Li, Lingjun.,Zhang, Chi.,Shen, Yutan.,Tang, Mingjie.,...&Wang, Jianji.(2019).An integrated high-throughput strategy enables the discovery of multifunctional ionic liquids for sustainable chemical processes.GREEN CHEMISTRY,21(2),307-313. |
| MLA | Zhu, Anlian,et al."An integrated high-throughput strategy enables the discovery of multifunctional ionic liquids for sustainable chemical processes".GREEN CHEMISTRY 21.2(2019):307-313. |
入库方式： OAI收割
来源：过程工程研究所
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