Self-supporting lithiophilic N-doped carbon rod array for dendrite-free lithium metal anode
文献类型：期刊论文
| 作者 | Chen, Lijuan1; Chen, Han1; Wang, Zhi2; Gong, Xuzhong2; Chen, Xianhong1; Wang, Mingyong2,3; Jiao, Shuqiang3 |
| 刊名 | CHEMICAL ENGINEERING JOURNAL
 |
| 出版日期 | 2019-05-01 |
| 卷号 | 363页码:270-277 |
| ISSN号 | 1385-8947 |
| 关键词 | Lithium metal Self-supporting Carbon rod array Lithiophilic N doping |
| DOI | 10.1016/j.cej.2019.01.131 |
| 英文摘要 | Carbon materials as host matrix of lithium (Li) anode attract more and more attention in order to inhibit uncontrollable dendritic growth of Li. Powdery carbon materials are usually synthesized and loaded on current collector by binder. The pore structure and active site of powdery materials will be easily destroyed during cycling. Herein, a self-supporting carbon film consisting of nitrogen (N)-doped carbon rod array (NCRA) with high N content and large surface area skeleton is developed as Li host matrix to regulate Li metal nucleation and suppress dendrites growth. The NCRA matrix exhibits low lithium loss mass and good long-term cycling stability during Li plating/stripping. The loss mass of Li in each cycle on NCRA is less than 0.01 mg cm(-2) at 1.0 mA cm(-2) and the value is much smaller than that (0.063 mg cm(-2)) on Cu foil. The Li vertical bar NCRA@Li symmetric cell has ultralong lifespan beyond 620 h and small voltage hysteresis of less than 40 mV at 2.0 mA cm(-2). The good electrochemical performance is ascribed to the stable self-supporting array structure for the storage of Li and abundant lithiophilic active sites for uniform Li electrodeposition in NCRA host matrix. Therefore, the dendritic growth of Li is effectively inhibited. This study provides a promising self-supporting lithiophilic NCRA as host material of Li anode to promote practical application in next-generation lithium-metal based batteries. |
| WOS关键词 | BATTERIES ; CHALLENGES ; NUCLEATION ; GROWTH |
| 资助项目 | Natural Science Foundation of China[51874020] ; Natural Science Foundation of China[21878299] |
| WOS研究方向 | Engineering |
| 语种 | 英语 |
| 出版者 | ELSEVIER SCIENCE SA |
| WOS记录号 | WOS:000457866400026 |
| 资助机构 | Natural Science Foundation of China |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/27894]  |
| 专题 | 中国科学院过程工程研究所 |
| 通讯作者 | Wang, Mingyong; Jiao, Shuqiang |
| 作者单位 | 1.Hunan Univ Technol, Coll Met & Mat Engn, Zhuzhou 412007, Peoples R China 2.Chinese Acad Sci, Natl Engn Lab Hydromet Cleaner Prod Technol, Key Lab Green Proc & Engn, Inst Proc Engn, Beijing 100190, Peoples R China 3.Univ Sci & Technol Beijing, State Key Lab Adv Met, Beijing 100083, Peoples R China |
| 推荐引用方式 GB/T 7714 | Chen, Lijuan,Chen, Han,Wang, Zhi,et al. Self-supporting lithiophilic N-doped carbon rod array for dendrite-free lithium metal anode[J]. CHEMICAL ENGINEERING JOURNAL,2019,363:270-277. |
| APA | Chen, Lijuan.,Chen, Han.,Wang, Zhi.,Gong, Xuzhong.,Chen, Xianhong.,...&Jiao, Shuqiang.(2019).Self-supporting lithiophilic N-doped carbon rod array for dendrite-free lithium metal anode.CHEMICAL ENGINEERING JOURNAL,363,270-277. |
| MLA | Chen, Lijuan,et al."Self-supporting lithiophilic N-doped carbon rod array for dendrite-free lithium metal anode".CHEMICAL ENGINEERING JOURNAL 363(2019):270-277. |
入库方式： OAI收割
来源：过程工程研究所
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