The dehydration of MgCl2 center dot 6H(2)O by inhibition of hydrolysis and conversion of hydrolysate
文献类型：期刊论文
| 作者 | Zhang, Zhimin; Lu, Xuchen; Yan, Yan; Wang, Tizhuang |
| 刊名 | JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS
 |
| 出版日期 | 2019-03-01 |
| 卷号 | 138页码:114-119 |
| 关键词 | Magnesium chloride hexahydrate Hydrolysis Anhydrous magnesium chloride Dehydration |
| ISSN号 | 0165-2370 |
| DOI | 10.1016/j.jaap.2018.12.014 |
| 英文摘要 | The hydrolysis of magnesium chloride hexahydrate and the countermeasures against hydrolysis were investigated. X-ray diffraction, TG-DSC analysis, and chemical analysis were employed to characterize the hydrolysis process, and then the hydrolysis reactions occurred at different temperatures were determined. After that, the combination of inhibition of hydrolysis and conversion of hydrolysate was adopted to cope with the different hydrolysis reactions. The hydrolysis process of MgCl2 center dot 6H(2)O includes the hydrolysis of dehydrated magnesium chloride below 300 degrees C with MgOHCl center dot xH(2)O as hydrolysate and the hydrolysis of anhydrous MgCl2 over 400 degrees C with MgO as hydrolysate. The inhibition of hydrolysis by forming dehydrated ammonium carnallite (below 300 degrees C) and the conversion of hydrolysate (above 400 degrees C) can effectively resolve the hydrolysis problem occurred at different stages. The dimension of the mixture of MgCl2 center dot 6H(2)O and NH4Cl influences the mass transfer and reaction process. When the ratio of height to diameter of the mixture was over 9:1, the magnesia content in anhydrous MgCl2 reached 0.1 wt.%. |
| WOS关键词 | ANHYDROUS MAGNESIUM-CHLORIDE ; THERMAL-DECOMPOSITION ; MGOHCL ; DTA |
| 资助项目 | National Science Foundation of China[51501178] ; Open Research Fund of State Key Laboratory of Multiphase Complex Systems[MPCS-2017-D-09] ; Autonomous Research Fund of State Key Laboratory of Multiphase Complex Systems[MPCS-2017-A-05] |
| WOS研究方向 | Chemistry ; Energy & Fuels ; Engineering |
| 语种 | 英语 |
| WOS记录号 | WOS:000457854800011 |
| 出版者 | ELSEVIER SCIENCE BV |
| 资助机构 | National Science Foundation of China ; Open Research Fund of State Key Laboratory of Multiphase Complex Systems ; Autonomous Research Fund of State Key Laboratory of Multiphase Complex Systems |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/27921]  |
| 专题 | 中国科学院过程工程研究所 |
| 通讯作者 | Lu, Xuchen |
| 作者单位 | Chinese Acad Sci, State Key Lab Multiphase Complex Syst, Inst Proc Engn, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Zhimin,Lu, Xuchen,Yan, Yan,et al. The dehydration of MgCl2 center dot 6H(2)O by inhibition of hydrolysis and conversion of hydrolysate[J]. JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS,2019,138:114-119. |
| APA | Zhang, Zhimin,Lu, Xuchen,Yan, Yan,&Wang, Tizhuang.(2019).The dehydration of MgCl2 center dot 6H(2)O by inhibition of hydrolysis and conversion of hydrolysate.JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS,138,114-119. |
| MLA | Zhang, Zhimin,et al."The dehydration of MgCl2 center dot 6H(2)O by inhibition of hydrolysis and conversion of hydrolysate".JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS 138(2019):114-119. |
入库方式： OAI收割
来源：过程工程研究所
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