Rational synthesis of silver nanowires at an electrode interface by diffusion limitation
文献类型：期刊论文
| 作者 | Liu, Wei1,2; Wang, Kai1,3; Zhou, Yu1; Guan, Xiaoping1; Che, Ping2; Han, Yongsheng1 |
| 刊名 | CRYSTENGCOMM
 |
| 出版日期 | 2019-03-07 |
| 卷号 | 21期号:9页码:1466-1473 |
| ISSN号 | 1466-8033 |
| DOI | 10.1039/c9ce00100j |
| 英文摘要 | We report an approach to synthesize silver nanowires by diffusion limitation. Silver particles are synthesized by electrochemical reaction in mixtures of silver nitrate solution and glycerol. Without glycerol, the main product is silver dendrites. With the addition of glycerol, silver nanowires are instead produced in abundance. The addition of glycerol increases the viscosity of the solvent, which restricts the diffusion of silver ions. Under conditions of diffusion limitation, a rapid electrochemical reaction leads to the formation of a chemical concentration gradient at the growth front of the nuclei, which results in the formation of silver dendritic structures. The increase of solvent viscosity attenuates the concentration gradient, which limits secondary nucleation on the sides of the silver rods, leading to the formation of 1D silver nanowires instead of dendrites. An increase of silver salt concentration sharpens the concentration gradient, which leads to the formation of dendritic structures again, confirming the dominant role of the interface chemical distribution in the structural evolution of the product materials. The silver nanowires synthesized are used to fabricate a conductive film by vacuum filtration followed by fixing and welding processes. The film shows high conductivity and excellent flexibility. |
| WOS关键词 | CHEMICAL DIFFUSION ; COMPOSITE FILMS ; NANOPARTICLES ; AGGREGATION ; DENDRITES ; GROWTH ; SENSOR |
| 资助项目 | National Key R&D Program of China[2017YFE0106500] ; National Natural Science Foundation of China[91534123] ; National Natural Science Foundation of China[91834303] ; National Natural Science Foundation of China[U1862117] ; Hundreds Talent Program from the Chinese Academy of Sciences ; State Key Laboratory of Multiphase Complex Systems[MPCS-2017-A-01] |
| WOS研究方向 | Chemistry ; Crystallography |
| 语种 | 英语 |
| WOS记录号 | WOS:000459740000011 |
| 出版者 | ROYAL SOC CHEMISTRY |
| 资助机构 | National Key R&D Program of China ; National Natural Science Foundation of China ; Hundreds Talent Program from the Chinese Academy of Sciences ; State Key Laboratory of Multiphase Complex Systems |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/28040]  |
| 专题 | 中国科学院过程工程研究所 |
| 通讯作者 | Han, Yongsheng |
| 作者单位 | 1.Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing 100190, Peoples R China 2.Univ Sci & Technol Beijing, Sch Chem & Biol Engn, Beijing 100083, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, Wei,Wang, Kai,Zhou, Yu,et al. Rational synthesis of silver nanowires at an electrode interface by diffusion limitation[J]. CRYSTENGCOMM,2019,21(9):1466-1473. |
| APA | Liu, Wei,Wang, Kai,Zhou, Yu,Guan, Xiaoping,Che, Ping,&Han, Yongsheng.(2019).Rational synthesis of silver nanowires at an electrode interface by diffusion limitation.CRYSTENGCOMM,21(9),1466-1473. |
| MLA | Liu, Wei,et al."Rational synthesis of silver nanowires at an electrode interface by diffusion limitation".CRYSTENGCOMM 21.9(2019):1466-1473. |
入库方式： OAI收割
来源：过程工程研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。