Solubility and dissolution mechanism of 4-chlorotoluene in subcritical water investigated in a fused silica capillary reactor by in situ Raman spectroscopy
文献类型:期刊论文
作者 | Chou, I-Ming1![]() |
刊名 | FLUID PHASE EQUILIBRIA
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出版日期 | 2016-10-15 |
卷号 | 425页码:93-97 |
关键词 | Subcritical Water 4-chlorotoluene Solubility Fused Silica Capillary Reactor Raman Spectroscopy |
DOI | 10.1016/j.fluid.2016.05.018 |
文献子类 | Article |
英文摘要 | The solubility of 4-chlorotoluene in subcritical water was measured using an optically transparent fused silica capillary reactor (FSCR). The total dissolution temperature of 4-chlorotoluene in subcritical water was visually determined. The dissolution uniformity of 4-chlorotoluene in subcritical water was confirmed by Raman spectroscopy. The solubility of 4-chlorotoluene linearly increased with increasing temperature in the range 262.3-293.8 degrees C. The dissolution mechanism of 4-chlorotoluene in subcritical water is proposed based on the Raman spectra of 4-chlorotoluene and water during the dissolution process in the FSCR. (C) 2016 Elsevier B.V. All rights reserved. |
URL标识 | 查看原文 |
WOS关键词 | HOT-COMPRESSED WATER ; POLYCYCLIC AROMATIC-HYDROCARBONS ; SUPERCRITICAL WATER ; PHASE-EQUILIBRIA ; DEGREES-C ; 473 K ; TEMPERATURES ; OXIDATION ; SYSTEMS ; DEPOLYMERIZATION |
语种 | 英语 |
WOS记录号 | WOS:000382341700013 |
版本 | 同行评议接收稿 |
源URL | [http://ir.idsse.ac.cn/handle/183446/1539] ![]() |
专题 | 深海科学研究部_深海极端环境模拟研究实验室 |
作者单位 | 1.Chinese Acad Sci, Sanya Inst Deep Sea Sci & Engn, Lab Expt Study Deep Sea Extreme Condit, Sanya 572000, Peoples R China 2.Zhejiang Univ Technol, Dept Environm Sci & Engn, Hangzhou 310032, Zhejiang, Peoples R China |
推荐引用方式 GB/T 7714 | Chou, I-Ming,Bei, Ke,Zhang, Chuanyong,et al. Solubility and dissolution mechanism of 4-chlorotoluene in subcritical water investigated in a fused silica capillary reactor by in situ Raman spectroscopy[J]. FLUID PHASE EQUILIBRIA,2016,425:93-97. |
APA | Chou, I-Ming.,Bei, Ke.,Zhang, Chuanyong.,Wang, Junliang.,Li, Kai.,...&Pan, Zhiyan.(2016).Solubility and dissolution mechanism of 4-chlorotoluene in subcritical water investigated in a fused silica capillary reactor by in situ Raman spectroscopy.FLUID PHASE EQUILIBRIA,425,93-97. |
MLA | Chou, I-Ming,et al."Solubility and dissolution mechanism of 4-chlorotoluene in subcritical water investigated in a fused silica capillary reactor by in situ Raman spectroscopy".FLUID PHASE EQUILIBRIA 425(2016):93-97. |
入库方式: OAI收割
来源:深海科学与工程研究所
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