中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Solubility and dissolution mechanism of 4-chlorotoluene in subcritical water investigated in a fused silica capillary reactor by in situ Raman spectroscopy

文献类型:期刊论文

作者Chou, I-Ming1; Bei, Ke2; Zhang, Chuanyong2; Wang, Junliang2; Li, Kai2; Lyu, Jinghui2; Zhao, Jia2; Chen, Jie2; Pan, Zhiyan2
刊名FLUID PHASE EQUILIBRIA
出版日期2016-10-15
卷号425页码:93-97
关键词Subcritical Water 4-chlorotoluene Solubility Fused Silica Capillary Reactor Raman Spectroscopy
DOI10.1016/j.fluid.2016.05.018
文献子类Article
英文摘要The solubility of 4-chlorotoluene in subcritical water was measured using an optically transparent fused silica capillary reactor (FSCR). The total dissolution temperature of 4-chlorotoluene in subcritical water was visually determined. The dissolution uniformity of 4-chlorotoluene in subcritical water was confirmed by Raman spectroscopy. The solubility of 4-chlorotoluene linearly increased with increasing temperature in the range 262.3-293.8 degrees C. The dissolution mechanism of 4-chlorotoluene in subcritical water is proposed based on the Raman spectra of 4-chlorotoluene and water during the dissolution process in the FSCR. (C) 2016 Elsevier B.V. All rights reserved.
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WOS关键词HOT-COMPRESSED WATER ; POLYCYCLIC AROMATIC-HYDROCARBONS ; SUPERCRITICAL WATER ; PHASE-EQUILIBRIA ; DEGREES-C ; 473 K ; TEMPERATURES ; OXIDATION ; SYSTEMS ; DEPOLYMERIZATION
语种英语
WOS记录号WOS:000382341700013
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源URL[http://ir.idsse.ac.cn/handle/183446/1539]  
专题深海科学研究部_深海极端环境模拟研究实验室
作者单位1.Chinese Acad Sci, Sanya Inst Deep Sea Sci & Engn, Lab Expt Study Deep Sea Extreme Condit, Sanya 572000, Peoples R China
2.Zhejiang Univ Technol, Dept Environm Sci & Engn, Hangzhou 310032, Zhejiang, Peoples R China
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GB/T 7714
Chou, I-Ming,Bei, Ke,Zhang, Chuanyong,et al. Solubility and dissolution mechanism of 4-chlorotoluene in subcritical water investigated in a fused silica capillary reactor by in situ Raman spectroscopy[J]. FLUID PHASE EQUILIBRIA,2016,425:93-97.
APA Chou, I-Ming.,Bei, Ke.,Zhang, Chuanyong.,Wang, Junliang.,Li, Kai.,...&Pan, Zhiyan.(2016).Solubility and dissolution mechanism of 4-chlorotoluene in subcritical water investigated in a fused silica capillary reactor by in situ Raman spectroscopy.FLUID PHASE EQUILIBRIA,425,93-97.
MLA Chou, I-Ming,et al."Solubility and dissolution mechanism of 4-chlorotoluene in subcritical water investigated in a fused silica capillary reactor by in situ Raman spectroscopy".FLUID PHASE EQUILIBRIA 425(2016):93-97.

入库方式: OAI收割

来源:深海科学与工程研究所

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