Acquisition and evaluation of thermodynamic data for mirabilite-thenardite equilibria at 0.1 MPa
文献类型：期刊论文
| 作者 | I-Ming Chou ; Hou, Xianhua1,2; Wang, Yunsheng1,2; Chou, I-Ming3; Zheng, Mianping1,2
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| 刊名 | JOURNAL OF CHEMICAL THERMODYNAMICS
 |
| 出版日期 | 2017-08-01 |
| 卷号 | 111期号:2017页码:221-227 |
| 关键词 | Mirabilite Thenardite Humidity Buffer Thermodynamic Properties |
| DOI | 10.1016/j.jct.2017.03.028 |
| 文献子类 | Article |
| 英文摘要 | Mirabilite and thenardite are common minerals found in marine evaporite deposits and also in saline lakes as precipitates. In this study, mirabilite-thenardite equilibria were determined along four humidity-buffer curves at 0.1 MPa and between 285.15 K and 305.15 K. Results for the reaction Na(2)SO(4 center dot)10H(2)O((s)) = Na2SO4(s) + 10H(2)O((g)), based on tight reversals along each humidity buffer, can be represented by ln K = 174.032-62815.11/T, where s is solid, g is gas, K is the equilibrium constant and T is temperature in K. Our data are in excellent agreement with several previous vapor-pressure measurements and are consistent with the solubility data reported in the literature. Thermodynamic analysis of these data yields 90.858 kJ.mol (1) for the standard Gibbs free energy of reaction, which is in good agreement with the values of 90.69 kJ.mol 1 and 90.34 kJ.mol (1) calculated from the thermodynamic data compiled and evaluated previously from two sources. (C) 2017 Elsevier Ltd. |
| WOS关键词 | SODIUM-SULFATE DECAHYDRATE ; HUMIDITY-BUFFER TECHNIQUE ; HYDRATED CRYSTALS ; VAPOR-PRESSURE ; SALT ; HEPTAHYDRATE ; DISSOCIATION ; HEATS ; CRYSTALLIZATION ; STABILITY |
| 语种 | 英语 |
| WOS记录号 | WOS:000402482500024 |
| 版本 | 出版稿 |
| 源URL | [http://ir.idsse.ac.cn/handle/183446/1708]  |
| 专题 | 深海科学研究部_深海极端环境模拟研究实验室 |
| 通讯作者 | I-Ming Chou |
| 作者单位 | 1.Chinese Acad Geol Sci, R&D Ctr Saline Lakes & Epithermal Deposits, Beijing 100037, Peoples R China 2.CAGS, MLR Key Lab Saline Lake Resources & Environm, Inst Mineral Resources, Beijing 100037, Peoples R China 3.Chinese Acad Sci, Inst Deep Sea Sci & Engn, Sanya 572000, Hainan, Peoples R China |
| 推荐引用方式 GB/T 7714 | I-Ming Chou,Hou, Xianhua,Wang, Yunsheng,et al. Acquisition and evaluation of thermodynamic data for mirabilite-thenardite equilibria at 0.1 MPa[J]. JOURNAL OF CHEMICAL THERMODYNAMICS,2017,111(2017):221-227. |
| APA | I-Ming Chou,Hou, Xianhua,Wang, Yunsheng,Chou, I-Ming,&Zheng, Mianping.(2017).Acquisition and evaluation of thermodynamic data for mirabilite-thenardite equilibria at 0.1 MPa.JOURNAL OF CHEMICAL THERMODYNAMICS,111(2017),221-227. |
| MLA | I-Ming Chou,et al."Acquisition and evaluation of thermodynamic data for mirabilite-thenardite equilibria at 0.1 MPa".JOURNAL OF CHEMICAL THERMODYNAMICS 111.2017(2017):221-227. |
入库方式： OAI收割
来源：深海科学与工程研究所
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