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Chinese Academy of Sciences Institutional Repositories Grid
Raman spectroscopic measurements of (1) band of hydrogen sulfide over a wide range of temperature and density in fused-silica optical cells

文献类型:期刊论文

作者Chou, I-Ming1; Chen, Ying1; Xin, Yang1,2; Jiang, Lei1
刊名JOURNAL OF RAMAN SPECTROSCOPY
出版日期2018-02-01
卷号49期号:2页码:343-350
关键词Density Fused-silica Optical Cells Hydrogen Sulfide Raman Spectroscopy Temperature
DOI10.1002/jrs.5293
文献子类Article
英文摘要

A method was developed to determine the fluid density of pure hydrogen sulfide (H2S) at a fixed temperature using Raman spectroscopic measurements. The positions of the H2S Raman (1) band were measured at a wide range of temperatures (188.15KT633.15K) and pressures (P506bar) using fused-silica capillary capsules and high-pressure optical cells. The relation among H2S density (), H2S (1) peak position, and T can be represented by =2447.680+0.127xT-1.876x(1)-0.000001xT(2)-0.000048x Tx(1)+0.00036x(1)(2) (root-mean-square error=0.0197g/cm(3) and correlation coefficient=0.9963). This equation can be applied to calculate the density of the H2S fluid from the measured H2S (1) peak position at a given temperature. Finally, the effects of temperature and H2S density on (1) peak position were examined using isochoric and isothermal experiments.

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WOS关键词High-pressure Phase ; Fluid Inclusions ; Carbon-dioxide ; Liquid-state ; Natural-gas ; H2s ; Co2 ; Calibration ; Spectra ; Water
语种英语
WOS记录号WOS:000425020500017
版本出版稿
源URL[http://ir.idsse.ac.cn/handle/183446/5925]  
专题深海科学研究部_深海极端环境模拟研究实验室
通讯作者Chou, I-Ming; Jiang, Lei
作者单位1.Chinese Acad Sci, Inst Deep Sea Sci & Engn, CAS Key Lab Expt Study Deep Sea Extreme Condit, Sanya 572000, Hainan, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式
GB/T 7714
Chou, I-Ming,Chen, Ying,Xin, Yang,et al. Raman spectroscopic measurements of (1) band of hydrogen sulfide over a wide range of temperature and density in fused-silica optical cells[J]. JOURNAL OF RAMAN SPECTROSCOPY,2018,49(2):343-350.
APA Chou, I-Ming,Chen, Ying,Xin, Yang,&Jiang, Lei.(2018).Raman spectroscopic measurements of (1) band of hydrogen sulfide over a wide range of temperature and density in fused-silica optical cells.JOURNAL OF RAMAN SPECTROSCOPY,49(2),343-350.
MLA Chou, I-Ming,et al."Raman spectroscopic measurements of (1) band of hydrogen sulfide over a wide range of temperature and density in fused-silica optical cells".JOURNAL OF RAMAN SPECTROSCOPY 49.2(2018):343-350.

入库方式: OAI收割

来源:深海科学与工程研究所

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