Raman spectroscopic measurements of (1) band of hydrogen sulfide over a wide range of temperature and density in fused-silica optical cells
文献类型:期刊论文
作者 | Chou, I-Ming1![]() ![]() ![]() ![]() |
刊名 | JOURNAL OF RAMAN SPECTROSCOPY
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出版日期 | 2018-02-01 |
卷号 | 49期号:2页码:343-350 |
关键词 | Density Fused-silica Optical Cells Hydrogen Sulfide Raman Spectroscopy Temperature |
DOI | 10.1002/jrs.5293 |
文献子类 | Article |
英文摘要 | A method was developed to determine the fluid density of pure hydrogen sulfide (H2S) at a fixed temperature using Raman spectroscopic measurements. The positions of the H2S Raman (1) band were measured at a wide range of temperatures (188.15KT633.15K) and pressures (P506bar) using fused-silica capillary capsules and high-pressure optical cells. The relation among H2S density (), H2S (1) peak position, and T can be represented by =2447.680+0.127xT-1.876x(1)-0.000001xT(2)-0.000048x Tx(1)+0.00036x(1)(2) (root-mean-square error=0.0197g/cm(3) and correlation coefficient=0.9963). This equation can be applied to calculate the density of the H2S fluid from the measured H2S (1) peak position at a given temperature. Finally, the effects of temperature and H2S density on (1) peak position were examined using isochoric and isothermal experiments. |
URL标识 | 查看原文 |
WOS关键词 | High-pressure Phase ; Fluid Inclusions ; Carbon-dioxide ; Liquid-state ; Natural-gas ; H2s ; Co2 ; Calibration ; Spectra ; Water |
语种 | 英语 |
WOS记录号 | WOS:000425020500017 |
版本 | 出版稿 |
源URL | [http://ir.idsse.ac.cn/handle/183446/5925] ![]() |
专题 | 深海科学研究部_深海极端环境模拟研究实验室 |
通讯作者 | Chou, I-Ming; Jiang, Lei |
作者单位 | 1.Chinese Acad Sci, Inst Deep Sea Sci & Engn, CAS Key Lab Expt Study Deep Sea Extreme Condit, Sanya 572000, Hainan, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
推荐引用方式 GB/T 7714 | Chou, I-Ming,Chen, Ying,Xin, Yang,et al. Raman spectroscopic measurements of (1) band of hydrogen sulfide over a wide range of temperature and density in fused-silica optical cells[J]. JOURNAL OF RAMAN SPECTROSCOPY,2018,49(2):343-350. |
APA | Chou, I-Ming,Chen, Ying,Xin, Yang,&Jiang, Lei.(2018).Raman spectroscopic measurements of (1) band of hydrogen sulfide over a wide range of temperature and density in fused-silica optical cells.JOURNAL OF RAMAN SPECTROSCOPY,49(2),343-350. |
MLA | Chou, I-Ming,et al."Raman spectroscopic measurements of (1) band of hydrogen sulfide over a wide range of temperature and density in fused-silica optical cells".JOURNAL OF RAMAN SPECTROSCOPY 49.2(2018):343-350. |
入库方式: OAI收割
来源:深海科学与工程研究所
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