Selective CO oxidation with real methanol reformate over monolithic Pt group catalysts: PEMFC applications
文献类型：期刊论文
| 作者 | Zhou, SL; Yuan, ZS; Wang, SD |
| 刊名 | international journal of hydrogen energy
 |
| 出版日期 | 2006-06-01 |
| 卷号 | 31期号:7页码:924-933 |
| 关键词 | PEMFC selective CO oxidation PROX hydrogen purification |
| 产权排序 | 1;1 |
| 通讯作者 | 王树东 |
| 英文摘要 | alumina supported pt group metal monolithic catalysts were investigated for selective oxidation of co in hydrogen-rich methanol reforming gas for proton exchange membrane fuel cell (pemfc) applications. the results are described and discussed in the present paper and show that pt/gamma al2o3 was the most promising candidate to selectively oxidize co from an amount of about 1 vol% to less than 100 ppm. we have investigated the effect of the o-2 to co feed ratio, the feed concentration of co, the presence of h2o and/or co2, and the space velocity on the activity, selectivity and stability of pt/al2o3 monolithic catalysts. afterwards, the pt/al2o3 catalyst was scaled up and applied in 5 kw hydrogen producing systems based on methanol steam reforming and autothermal reforming. the hydrogen produced was then used as fuel for an integrated pemfc. (c) 2005 international association for hydrogen energy. published by elsevier ltd. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences ; technology |
| 类目[WOS] | chemistry, physical ; electrochemistry ; energy & fuels |
| 研究领域[WOS] | chemistry ; electrochemistry ; energy & fuels |
| 关键词[WOS] | supported au catalysts ; fuel-cell applications ; preferential oxidation ; carbon-monoxide ; excess hydrogen ; h-2-rich gas ; oxide catalysts ; ru catalyst ; removal ; performance |
| 收录类别 | SCI |
| 原文出处 | true |
| 语种 | 英语 |
| WOS记录号 | WOS:000237639400015 |
| 公开日期 | 2010-11-30 |
| 源URL | [http://159.226.238.44/handle/321008/97735]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhou, SL,Yuan, ZS,Wang, SD. Selective CO oxidation with real methanol reformate over monolithic Pt group catalysts: PEMFC applications[J]. international journal of hydrogen energy,2006,31(7):924-933. |
| APA | Zhou, SL,Yuan, ZS,&Wang, SD.(2006).Selective CO oxidation with real methanol reformate over monolithic Pt group catalysts: PEMFC applications.international journal of hydrogen energy,31(7),924-933. |
| MLA | Zhou, SL,et al."Selective CO oxidation with real methanol reformate over monolithic Pt group catalysts: PEMFC applications".international journal of hydrogen energy 31.7(2006):924-933. |
入库方式： OAI收割
来源：大连化学物理研究所
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