Gas chromatographic peak identification for polybrominated diphenyl ethers under different temperature programs
文献类型:期刊论文
作者 | Zhao, HX; Xue, XY; Xu, Q; Zhang, FF; Liang, XM |
刊名 | journal of chromatography a
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出版日期 | 2006-02-24 |
卷号 | 1107期号:1-2页码:248-256 |
关键词 | polybrominated diphenyl ethers prediction chromatographic retention parameters molecular connectivity indexes |
产权排序 | 1;1 |
通讯作者 | 梁鑫淼 |
英文摘要 | a method has been developed for gas chromatographic peak recognition of polybrominated diphenyl ethers (pbdes) under different temperature programs. on the basis of an identification database of retention parameters (a, b values) of gas chromatography and retention times of the selected internal standards, the retention times of bdes can be accurately estimated. in comparison with the experimental retention values, the predicted retention times have been proved to be very accurate. in addition, owing to only a part of bde analytical standards are available, using 40 bdes as a training set, the quantitative relationship between retention parameters of bdes and molecular connectivity indexes has been found. the correlation coefficients are greater than 0.997. the a, b values of all the remaining 169 bde congeners have been predicted. (c) 2005 elsevier b.v. all rights reserved. |
WOS标题词 | science & technology ; life sciences & biomedicine ; physical sciences |
类目[WOS] | biochemical research methods ; chemistry, analytical |
研究领域[WOS] | biochemistry & molecular biology ; chemistry |
关键词[WOS] | flame retardants ; pbdes ; perspective ; congeners ; ocean |
收录类别 | SCI |
原文出处 | true |
语种 | 英语 |
WOS记录号 | WOS:000235505100031 |
公开日期 | 2010-11-30 |
源URL | [http://159.226.238.44/handle/321008/97795] ![]() |
专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
作者单位 | Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China |
推荐引用方式 GB/T 7714 | Zhao, HX,Xue, XY,Xu, Q,et al. Gas chromatographic peak identification for polybrominated diphenyl ethers under different temperature programs[J]. journal of chromatography a,2006,1107(1-2):248-256. |
APA | Zhao, HX,Xue, XY,Xu, Q,Zhang, FF,&Liang, XM.(2006).Gas chromatographic peak identification for polybrominated diphenyl ethers under different temperature programs.journal of chromatography a,1107(1-2),248-256. |
MLA | Zhao, HX,et al."Gas chromatographic peak identification for polybrominated diphenyl ethers under different temperature programs".journal of chromatography a 1107.1-2(2006):248-256. |
入库方式: OAI收割
来源:大连化学物理研究所
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