New efficient organocatalytic oxidation of benzylic compounds by molecular oxygen under mild conditions
文献类型：期刊论文
| 作者 | Tong, XL; Xu, J; Miao, H; Gao, J |
| 刊名 | tetrahedron letters
 |
| 出版日期 | 2006-03-13 |
| 卷号 | 47期号:11页码:1763-1766 |
| 关键词 | benzylic oxidation organocatalysis molecular oxygen acridine yellow |
| 产权排序 | 1;1 |
| 通讯作者 | 徐杰 |
| 英文摘要 | efficient aerobic oxidation of benzylic compounds has been achieved under no irradiation using a new organocatalytic system in the presence of acridine yellow and n-hydroxyphthalimide with assistance of a catalytic amount of molecular bromine. various substrates, especially alkylaromatics, were effectively oxygenated to the corresponding carbonyl compounds with molecular oxygen as oxidant under mild conditions. for instance, indan was oxidized with 92% conversion and 79% selectivity for i-indanone under 0.3 mpa of o-2 at 75 degrees c. (c) 2006 elsevier ltd. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, organic |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | n-hydroxyphthalimide nhpi ; photoinduced electron-transfer ; catalytic-system ; selective oxygenation ; aromatic-compounds ; hydrogen-peroxide ; aerobic oxidation ; metal-free ; alkylbenzenes ; alcohols |
| 收录类别 | SCI ; CCR |
| 原文出处 | true |
| 语种 | 英语 |
| WOS记录号 | WOS:000235647300018 |
| 公开日期 | 2010-11-30 |
| 源URL | [http://159.226.238.44/handle/321008/97849]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Grad Sch, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Tong, XL,Xu, J,Miao, H,et al. New efficient organocatalytic oxidation of benzylic compounds by molecular oxygen under mild conditions[J]. tetrahedron letters,2006,47(11):1763-1766. |
| APA | Tong, XL,Xu, J,Miao, H,&Gao, J.(2006).New efficient organocatalytic oxidation of benzylic compounds by molecular oxygen under mild conditions.tetrahedron letters,47(11),1763-1766. |
| MLA | Tong, XL,et al."New efficient organocatalytic oxidation of benzylic compounds by molecular oxygen under mild conditions".tetrahedron letters 47.11(2006):1763-1766. |
入库方式： OAI收割
来源：大连化学物理研究所
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