The oxygen activated by the active vanadium species for the selective oxidation of benzene to phenol
文献类型：期刊论文
| 作者 | Gao, Xiaohan; Xu, Jie |
| 刊名 | catalysis letters
 |
| 出版日期 | 2006-11-01 |
| 卷号 | 111期号:3-4页码:203-205 |
| 关键词 | activation of oxygen active vanadium species selective oxidation benzene phenol |
| 产权排序 | 1;1 |
| 通讯作者 | 徐杰 |
| 英文摘要 | the activation of oxygen is a key step for the selective oxidation of benzene to phenol and the reason is discussed. the active oxygen species is produced from molecular oxygen in a so-called "reductive activation" process. the vanadium oxide supported on alumina was pre-reduced by hydrogen or ascorbic acid to lower valence vanadium species acting as reduction source and the activity is investigated in the reaction. it is found that the v4+ valence vanadium (vo2+) is effective for the reaction from the characterization of catalysts by xps. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, physical |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | liquid-phase oxidation ; x-ray electron ; hydrogen-peroxide ; spectroscopy ; catalysts ; oxides ; zeolites ; hydroxylation ; iron |
| 收录类别 | SCI |
| 原文出处 | true |
| 语种 | 英语 |
| WOS记录号 | WOS:000241578200015 |
| 公开日期 | 2010-11-30 |
| 源URL | [http://159.226.238.44/handle/321008/97865]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Gao, Xiaohan,Xu, Jie. The oxygen activated by the active vanadium species for the selective oxidation of benzene to phenol[J]. catalysis letters,2006,111(3-4):203-205. |
| APA | Gao, Xiaohan,&Xu, Jie.(2006).The oxygen activated by the active vanadium species for the selective oxidation of benzene to phenol.catalysis letters,111(3-4),203-205. |
| MLA | Gao, Xiaohan,et al."The oxygen activated by the active vanadium species for the selective oxidation of benzene to phenol".catalysis letters 111.3-4(2006):203-205. |
入库方式： OAI收割
来源：大连化学物理研究所
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