Deep desulfurization from fuel oil via selective oxidation using an amphiphilic peroxotungsten catalyst assembled in emulsion droplets
文献类型：期刊论文
| 作者 | Gao, Jinbo; Wang, Shouguo; Jiang, Zongxuan; Lu, Hongying; Yang, Yongxing; Jing, Fei; Li, Can |
| 刊名 | journal of molecular catalysis a-chemical
 |
| 出版日期 | 2006-10-02 |
| 卷号 | 258期号:1-2页码:261-266 |
| 关键词 | recoverable catalysts desulfurization emulsion catalysis oxidation sulfides diesel gasoline |
| 产权排序 | 1;1 |
| 通讯作者 | 李灿 |
| 英文摘要 | a recyclable amphiphilic catalyst, which composed of peroxotungsten anion and quaternary ammonium cation assembled in the interface of the emulsion droplets, shows high selectivity and activity in the oxidation of sulfur-containing molecules to sulfones with hydrogen peroxide in diesel under mild reaction conditions. all the sulfur-containing molecules present in diesel can be completely oxidized into sulfones with -100% selectivity of sulfones in w/o (h2o2-in-diesel) emulsion system. the sulfones can be readily separated from the diesel, and the sulfur level of the desulfurized diesel can be lowered from about 500 ppm to below 1 ppm with about 98% yield of oil. in addition, the s-containing molecules in straight-run gas oil are also readily oxidized to their corresponding products in the oav emulsion reaction medium. the s-level of oil layer of the oxidized oil was reduced to below 1 ppm from 312 ppm in the original straight-run gas oil with above 99% yield of oil. the amphiphilic catalysts serve as not only a catalyst but also an emulsifying agent to stabilize the emulsion droplets. the emulsion droplets are not only in the highly dispersed form but also behave like homogenous catalyst with high activity. the limitations due to interphase mass transport are greatly reduced in emulsion reaction medium. moreover, the emulsion catalysts can be easily separated and recycled by demulsifying. (c) 2006 elsevier b.v. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, physical |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | phase-transfer catalysis ; aqueous surfactant solutions ; light gas oil ; hydrogen-peroxide ; alkylphenyl ethers ; organic-synthesis ; reaction media ; diesel fuel ; lewis-acid ; water |
| 收录类别 | SCI |
| 原文出处 | true |
| 语种 | 英语 |
| WOS记录号 | WOS:000241173700036 |
| 公开日期 | 2010-11-30 |
| 源URL | [http://159.226.238.44/handle/321008/98241]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Gao, Jinbo,Wang, Shouguo,Jiang, Zongxuan,et al. Deep desulfurization from fuel oil via selective oxidation using an amphiphilic peroxotungsten catalyst assembled in emulsion droplets[J]. journal of molecular catalysis a-chemical,2006,258(1-2):261-266. |
| APA | Gao, Jinbo.,Wang, Shouguo.,Jiang, Zongxuan.,Lu, Hongying.,Yang, Yongxing.,...&Li, Can.(2006).Deep desulfurization from fuel oil via selective oxidation using an amphiphilic peroxotungsten catalyst assembled in emulsion droplets.journal of molecular catalysis a-chemical,258(1-2),261-266. |
| MLA | Gao, Jinbo,et al."Deep desulfurization from fuel oil via selective oxidation using an amphiphilic peroxotungsten catalyst assembled in emulsion droplets".journal of molecular catalysis a-chemical 258.1-2(2006):261-266. |
入库方式： OAI收割
来源：大连化学物理研究所
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