A Methanol Concentration Sensor Using Twin Membrane Electrode Assemblies for Direct Methanol Fuel Cells
文献类型:期刊论文
作者 | Sun, Wei1,2; Sun, Gongquan1; Yang, Weiqian1,2; Yang, Shaohua1; Xin, Qin1 |
刊名 | international journal of electrochemical science
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出版日期 | 2006-08-01 |
卷号 | 1期号:4页码:160-170 |
关键词 | Fuel cell Sensor Methanol concentration Membrane electrode assembly (MEA) |
产权排序 | 1;1 |
通讯作者 | 孙公权 |
英文摘要 | a methanol concentration sensor based on twin nafion membrane electrode assemblies (meas) was constructed with anodes face to face eliminating the interference of oxygen in environment. the signal of the sensor was obtained by electro-oxidation of the methanol crossing over nafion membranes from cathodes. during operation, carbon dioxide as a product of methanol oxidation not only was expelled from the gaps between two meas, but also permeated across the membranes into the cathodes, which was confirmed by gc in the outflowing stream of the sensor. electrochemical characterization shows that the sensor has good response performance with a concentration range up to 5m and the signal increases with temperature elevating. the slightly nonlinearity of the working curves was mainly caused by electro-osmotic effect confirmed by electro-osmotic drag coefficient. though logarithm tendency degradation with 0.9% hr(-1) was observed from stability test, the performances in terms of high sensitivity to concentration with wide measuring range and signal recovery characteristics show that the sensor is promising for direct methanol fuel cells. |
WOS标题词 | science & technology ; physical sciences |
类目[WOS] | electrochemistry |
研究领域[WOS] | electrochemistry |
收录类别 | SCI |
原文出处 | true |
语种 | 英语 |
WOS记录号 | WOS:000208126500002 |
公开日期 | 2010-11-30 |
源URL | [http://159.226.238.44/handle/321008/98301] ![]() |
专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Grad Sch, Dalian 116023, Peoples R China |
推荐引用方式 GB/T 7714 | Sun, Wei,Sun, Gongquan,Yang, Weiqian,et al. A Methanol Concentration Sensor Using Twin Membrane Electrode Assemblies for Direct Methanol Fuel Cells[J]. international journal of electrochemical science,2006,1(4):160-170. |
APA | Sun, Wei,Sun, Gongquan,Yang, Weiqian,Yang, Shaohua,&Xin, Qin.(2006).A Methanol Concentration Sensor Using Twin Membrane Electrode Assemblies for Direct Methanol Fuel Cells.international journal of electrochemical science,1(4),160-170. |
MLA | Sun, Wei,et al."A Methanol Concentration Sensor Using Twin Membrane Electrode Assemblies for Direct Methanol Fuel Cells".international journal of electrochemical science 1.4(2006):160-170. |
入库方式: OAI收割
来源:大连化学物理研究所
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