Solvent-free oxidation of alcohols catalyzed by an efficient and reusable heteropolyphosphatotungstate
文献类型：期刊论文
| 作者 | Zhang, Shengjun; Gao, Shuang; Xi, Zuwei; Xu, Jie |
| 刊名 | catalysis communications
 |
| 出版日期 | 2007-03-01 |
| 卷号 | 8期号:3页码:531-534 |
| 关键词 | alcohol oxidation solvent-free hydrogen peroxide heteropolyphosphatotungstate |
| 产权排序 | 1;1 |
| 通讯作者 | 高爽 |
| 英文摘要 | with aqueous hydrogen peroxide as oxidant, secondary alcohols could be efficiently oxidized to ketones in the presence of hexadecyl trimethyl ammonium heteropolyphosphatotungstate ((n-c16h33n(ch3)(3))(3)[pw4o16]) under solvent-free conditions. the oxidation of alcohol over 0.5 mol% (based on molar amount of hydrogen peroxide) catalyst occurred at 90 degrees c to give the corresponding ketones with above 92% yield and 97% selectivity. the catalyst could be reused without loss of selectivity. (c) 2006 elsevier b.v. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, physical |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | aqueous hydrogen-peroxide ; atom economy ; ketones ; epoxidation ; oxide |
| 收录类别 | SCI ; CCR |
| 原文出处 | true |
| 语种 | 英语 |
| WOS记录号 | WOS:000243163000062 |
| 公开日期 | 2010-11-30 |
| 源URL | [http://159.226.238.44/handle/321008/98657]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Shengjun,Gao, Shuang,Xi, Zuwei,et al. Solvent-free oxidation of alcohols catalyzed by an efficient and reusable heteropolyphosphatotungstate[J]. catalysis communications,2007,8(3):531-534. |
| APA | Zhang, Shengjun,Gao, Shuang,Xi, Zuwei,&Xu, Jie.(2007).Solvent-free oxidation of alcohols catalyzed by an efficient and reusable heteropolyphosphatotungstate.catalysis communications,8(3),531-534. |
| MLA | Zhang, Shengjun,et al."Solvent-free oxidation of alcohols catalyzed by an efficient and reusable heteropolyphosphatotungstate".catalysis communications 8.3(2007):531-534. |
入库方式： OAI收割
来源：大连化学物理研究所
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