Photochemistry of aryl halides: Photodissociation dynamics
文献类型：期刊论文
| 作者 | Han, Ke-Li; He, Guo-Zhong |
| 刊名 | journal of photochemistry and photobiology c-photochemistry reviews
 |
| 出版日期 | 2007-10-01 |
| 卷号 | 8期号:2页码:55-66 |
| 关键词 | photodissociation dynamics photofragment translational spectroscopy nonadiabatic process intersystem crossing ab initio calculation |
| 产权排序 | 1;1 |
| 通讯作者 | 韩克利 |
| 英文摘要 | in recent years, the photodissociation dynamics of aryl halides has been a subject of intensive studies, which is closely related to the atmospheric chemistry. here we present a review on the photochemistry of aryl halides, with emphasis on the recent progress in photodissociation dynamics at 266 nm by using photofragment translational spectroscopy. the ab initio calculations have also been employed to investigate those photodissociation processes. it has been found that the photodissociation of aryl halides at 266 nm is attributed to the nonadiabatic process via intersystem crossings from bound singlet excited state to triplet excited state and/or via internal conversion from bound singlet excited state to ground state. also, the substitution effects in the photodissociation dynamics of aryl halides are discussed. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, physical |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | pump-probe spectroscopy ; photofragment translational spectroscopy ; fourier-transform spectroscopy ; kinetic-energy spectroscopy ; supported nickel-catalysts ; orbit ab-initio ; internal-rotation ; 266 nm ; methyl-group ; aromatic-molecules |
| 收录类别 | SCI |
| 原文出处 | true |
| 语种 | 英语 |
| WOS记录号 | WOS:000250423700001 |
| 公开日期 | 2010-11-30 |
| 源URL | [http://159.226.238.44/handle/321008/98677]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Han, Ke-Li,He, Guo-Zhong. Photochemistry of aryl halides: Photodissociation dynamics[J]. journal of photochemistry and photobiology c-photochemistry reviews,2007,8(2):55-66. |
| APA | Han, Ke-Li,&He, Guo-Zhong.(2007).Photochemistry of aryl halides: Photodissociation dynamics.journal of photochemistry and photobiology c-photochemistry reviews,8(2),55-66. |
| MLA | Han, Ke-Li,et al."Photochemistry of aryl halides: Photodissociation dynamics".journal of photochemistry and photobiology c-photochemistry reviews 8.2(2007):55-66. |
入库方式： OAI收割
来源：大连化学物理研究所
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