A mechanistic investigation of the coupled reaction of n-hexane and methanol over HZSM-5
文献类型：期刊论文
| 作者 | Chang, Fuxiang; Wei, Yingxu; Liu, Xianbin; Zhao, Yinfeng; Xu, Lei; Sun, Ying; Zhang, Dazhi; He, Yanli; Liu, Zhongmin |
| 刊名 | applied catalysis a-general
 |
| 出版日期 | 2007-09-10 |
| 卷号 | 328期号:2页码:163-173 |
| 关键词 | coupled reaction n-hexane methanol ZSM-5 mechanism |
| 产权排序 | 1;1 |
| 通讯作者 | 刘中民 |
| 英文摘要 | the coupled reaction of n-hexane and methanol was studied and compared with the reactions of individual reactants over hzsm-5 zeolite catalyst. the catalytic reaction test results and the temperature-programmed surface reaction (tpsr) results showed an improvement of the initial n-hexane activity when methanol was used as co-reactant. the ft-ir analysis indicated that methanol was adsorbed on acid sites prior to n-hexane and immediately transformed into surface methoxy groups. these species acted as the active sites for the conversion of n-hexane and improved the initial activity of n-hexane by bimolecular hydride transfer. the catalytic test also suggested that alkenes resulting from the transformation of methanol further enhance the conversion of n-hexane, in addition to the improvement by metboxy groups. a faster conversion of methanol was also observed in the coupled system, which highlights a bidirectional promotion effect of the coupled reaction. a reaction mechanism is proposed to explain all observations. (c) 2007 elsevier b.v. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences ; life sciences & biomedicine |
| 类目[WOS] | chemistry, physical ; environmental sciences |
| 研究领域[WOS] | chemistry ; environmental sciences & ecology |
| 关键词[WOS] | nonclassical carbonium-ions ; catalytic cracking ; zeolite catalysts ; surface methoxy ; dimethyl ether ; light olefins ; hydrocarbon cracking ; chemical ionization ; acidic catalysts ; to-hydrocarbons |
| 收录类别 | SCI |
| 原文出处 | true |
| 语种 | 英语 |
| WOS记录号 | WOS:000249173300009 |
| 公开日期 | 2010-11-30 |
| 源URL | [http://159.226.238.44/handle/321008/98749]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Nat Gas Utilizat & Appl Catalysis Lab, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China |
| 推荐引用方式 GB/T 7714 | Chang, Fuxiang,Wei, Yingxu,Liu, Xianbin,et al. A mechanistic investigation of the coupled reaction of n-hexane and methanol over HZSM-5[J]. applied catalysis a-general,2007,328(2):163-173. |
| APA | Chang, Fuxiang.,Wei, Yingxu.,Liu, Xianbin.,Zhao, Yinfeng.,Xu, Lei.,...&Liu, Zhongmin.(2007).A mechanistic investigation of the coupled reaction of n-hexane and methanol over HZSM-5.applied catalysis a-general,328(2),163-173. |
| MLA | Chang, Fuxiang,et al."A mechanistic investigation of the coupled reaction of n-hexane and methanol over HZSM-5".applied catalysis a-general 328.2(2007):163-173. |
入库方式： OAI收割
来源：大连化学物理研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。