Selective oxidation of ethylbenzene by a biomimetic combination: Hemin and N-hydroxyphthalimide (NHPI)
文献类型：期刊论文
| 作者 | Ma, Hong; Xu, Jie; Zhang, Qiaohong; Miao, Hong; Wu, Wenhai |
| 刊名 | catalysis communications
 |
| 出版日期 | 2007 |
| 卷号 | 8期号:1页码:27-30 |
| 关键词 | ethylbenzene hemin N-hydroxyphthalimide oxidation |
| 产权排序 | 1;1 |
| 通讯作者 | 徐杰 |
| 英文摘要 | a biomimetic catalytic system consisting of hemin and n-hydroxyphthalimide (nhpi) for the selective oxidation of ethylbenzene with dioxygen is reported. 90.32% conversion of ethylbenzene with 94.30% selectivity for acetophenone (acpo) can be obtained at 100 degrees c under 0.3 mpa o-2 for 9 h. hemin can efficiently decompose in situ formed 1-phenylethyl hydroperoxide (pehp) with acpo as the main product. (c) 2006 elsevier b.v. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, physical |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | molecular-oxygen ; iron-porphyrins ; system ; metalloporphyrins ; hydroperoxides ; hydrocarbons ; cyclohexane ; epoxidation ; mechanism ; cleavage |
| 收录类别 | SCI ; CCR |
| 原文出处 | true |
| 语种 | 英语 |
| WOS记录号 | WOS:000242759500006 |
| 公开日期 | 2010-11-30 |
| 源URL | [http://159.226.238.44/handle/321008/98931]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | Chinese Acad Sci, Dalian Inst Chem Phys, Grad Sch, State Key Lab Catalysis, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Ma, Hong,Xu, Jie,Zhang, Qiaohong,et al. Selective oxidation of ethylbenzene by a biomimetic combination: Hemin and N-hydroxyphthalimide (NHPI)[J]. catalysis communications,2007,8(1):27-30. |
| APA | Ma, Hong,Xu, Jie,Zhang, Qiaohong,Miao, Hong,&Wu, Wenhai.(2007).Selective oxidation of ethylbenzene by a biomimetic combination: Hemin and N-hydroxyphthalimide (NHPI).catalysis communications,8(1),27-30. |
| MLA | Ma, Hong,et al."Selective oxidation of ethylbenzene by a biomimetic combination: Hemin and N-hydroxyphthalimide (NHPI)".catalysis communications 8.1(2007):27-30. |
入库方式： OAI收割
来源：大连化学物理研究所
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