Highly efficient and metal-free oxidation of olefins by molecular oxygen under mild conditions
文献类型：期刊论文
| 作者 | Tong, Xinli; Xu, Jie; Miao, Hong; Yang, Guanyu; Ma, Hong; Zhang, Qiaohong |
| 刊名 | tetrahedron
 |
| 出版日期 | 2007-08-06 |
| 卷号 | 63期号:32页码:7634-7639 |
| 关键词 | metal-free oxidation cyclohexene styrene N-hydroxyphthalimide |
| 产权排序 | 1;1 |
| 通讯作者 | 徐杰 |
| 英文摘要 | highly efficient and metal-free aerobic oxidations of cyclohexene and styrene were successfully performed under mild conditions in the presence of 1,4-diamino-2,3-dichloro-anthraquinone and n-hydroxyphthalimide. when cyclohexene was oxidized, an 89% conversion and 71% selectivity for 2-cyclohexen-1-one was obtained under 0.3 mpa at 80 degrees c for 5 h. in the oxidation of styrene, a 77% conversion and 69% selectivity for benzaldehyde was obtained for 10 h. furthermore, more olefins were efficiently oxidized to corresponding oxygenated products under mild conditions. all kinds of factors that affected cyclohexene oxidation were well investigated, and the possible reaction mechanism was provided. (c) 2007 elsevier ltd. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, organic |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | alumina-supported mn(ii) ; tert-butylhydroperoxide ; hydrogen-peroxide ; cyclohexene oxidation ; n-hydroxyphthalimide ; selective oxidation ; catalytic-oxidation ; allylic oxidation ; styrene oxidation ; acetic-acid |
| 收录类别 | SCI ; CCR |
| 原文出处 | true |
| 语种 | 英语 |
| WOS记录号 | WOS:000252082700017 |
| 公开日期 | 2010-11-30 |
| 源URL | [http://159.226.238.44/handle/321008/98937]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Grad Sch, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Tong, Xinli,Xu, Jie,Miao, Hong,et al. Highly efficient and metal-free oxidation of olefins by molecular oxygen under mild conditions[J]. tetrahedron,2007,63(32):7634-7639. |
| APA | Tong, Xinli,Xu, Jie,Miao, Hong,Yang, Guanyu,Ma, Hong,&Zhang, Qiaohong.(2007).Highly efficient and metal-free oxidation of olefins by molecular oxygen under mild conditions.tetrahedron,63(32),7634-7639. |
| MLA | Tong, Xinli,et al."Highly efficient and metal-free oxidation of olefins by molecular oxygen under mild conditions".tetrahedron 63.32(2007):7634-7639. |
入库方式： OAI收割
来源：大连化学物理研究所
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