AN environmentally benign route for epichlorohydrin from allyl chloride epoxidation catalyzed by heteropolyphosphatotungstate
文献类型：期刊论文
| 作者 | Li, Jian; Xi, Zuwei; Gao, Shuang |
| 刊名 | research on chemical intermediates
 |
| 出版日期 | 2007 |
| 卷号 | 33期号:6页码:523-534 |
| 关键词 | allyl chloride epoxidation heteropolyphosphatotungstate hydrogen peroxide |
| 产权排序 | 1;1 |
| 通讯作者 | 奚祖威 |
| 英文摘要 | in the absence of organic solvent, allyl chloride was epoxidized with aqueous hydrogen peroxide catalyzed by a heteropolyphosphatotungstate catalyst with very good activity and recycling activity. under optimized conditions, an epichlorohydrin yield of 88.7% was achieved in the first run; after two recycles, the epichlorohydrin yield remained still above 85.0%. various factors affecting the catalytic reaction were investigated systematically. the reaction rate of hydrogen peroxide in the epoxidation of allyl chloride is zero order with respect to hydrogen peroxide. the activation energy is 52.27 kj/mol. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, multidisciplinary |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | hydrogen-peroxide ; molecular-oxygen ; olefins |
| 收录类别 | SCI ; CCR |
| 原文出处 | true |
| 语种 | 英语 |
| WOS记录号 | WOS:000250112200005 |
| 公开日期 | 2010-11-30 |
| 源URL | [http://159.226.238.44/handle/321008/98945]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, Jian,Xi, Zuwei,Gao, Shuang. AN environmentally benign route for epichlorohydrin from allyl chloride epoxidation catalyzed by heteropolyphosphatotungstate[J]. research on chemical intermediates,2007,33(6):523-534. |
| APA | Li, Jian,Xi, Zuwei,&Gao, Shuang.(2007).AN environmentally benign route for epichlorohydrin from allyl chloride epoxidation catalyzed by heteropolyphosphatotungstate.research on chemical intermediates,33(6),523-534. |
| MLA | Li, Jian,et al."AN environmentally benign route for epichlorohydrin from allyl chloride epoxidation catalyzed by heteropolyphosphatotungstate".research on chemical intermediates 33.6(2007):523-534. |
入库方式： OAI收割
来源：大连化学物理研究所
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