Sulfonated polyimide/PTFE reinforced membrane for PEMFCs
文献类型：期刊论文
| 作者 | Wang, L.; Yi, B. L.; Zhang, H. M.; Liu, Y. H.; Xing, D. M.; Shao, Z.-G.; Cai, Y. H. |
| 刊名 | journal of power sources
 |
| 出版日期 | 2007-05-01 |
| 卷号 | 167期号:1页码:47-52 |
| 关键词 | PEMFC composite membrane sulfonated polyimide nafion multilayer |
| 产权排序 | 1;1 |
| 通讯作者 | 衣宝廉 |
| 英文摘要 | a sulfonated polyimide (spi)/ptfe reinforced membrane was synthesized by impregnating ptfe (porous polytetrafluoroethylene) membrane with a spi/dmso solution. the resulting composite membrane was mechanically durable and quite thin relative to traditional perfluorosulfonated ionomer membranes (pfsi). we expect the ptfe to restrict the swelling and dimensional change of the spi when it is immersed into water. and the reinforcement with ptfe can increase the hydrolysis stability of the spi due to the low swelling and low dimensional change. from ex-situ testing and a short term fuel cell "life" test, we conclude that the ptfe reinforced sulfonated polyimide had a higher hydrolytic stability than pure sulfonated polyimide. the thin spi/ptfe membrane showed comparable fuel cell performance with the commercial nre-212 membrane with h(2)/o(2) at 80 degrees c under fully humidified conditions. the chemically modified membrane with nation layer showed good stability in a 120 h fuel cell test. (c) 2007 elsevier b.v. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences ; technology |
| 类目[WOS] | electrochemistry ; energy & fuels |
| 研究领域[WOS] | electrochemistry ; energy & fuels |
| 关键词[WOS] | polymer electrolyte membranes ; fuel-cell applications ; proton conductivity ; composite membrane ; water stability ; acid ; polyelectrolytes |
| 收录类别 | SCI |
| 原文出处 | true |
| 语种 | 英语 |
| WOS记录号 | WOS:000246256300007 |
| 公开日期 | 2010-11-30 |
| 源URL | [http://159.226.238.44/handle/321008/98993]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Proton Exchange Membrane Fuel Cell Key Mat & Tech, Dalian 116023, Liaoning, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, L.,Yi, B. L.,Zhang, H. M.,et al. Sulfonated polyimide/PTFE reinforced membrane for PEMFCs[J]. journal of power sources,2007,167(1):47-52. |
| APA | Wang, L..,Yi, B. L..,Zhang, H. M..,Liu, Y. H..,Xing, D. M..,...&Cai, Y. H..(2007).Sulfonated polyimide/PTFE reinforced membrane for PEMFCs.journal of power sources,167(1),47-52. |
| MLA | Wang, L.,et al."Sulfonated polyimide/PTFE reinforced membrane for PEMFCs".journal of power sources 167.1(2007):47-52. |
入库方式： OAI收割
来源：大连化学物理研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。