Catalytic wet air oxidation of coke-plant wastewater on ruthenium-based eggshell catalysts in a bubbling bed reactor
文献类型：期刊论文
| 作者 | Yang, M.; Sun, Y.; Xu, A. H.; Lu, X. Y.; Du, H. Z.; Sun, C. L.; Li, C. |
| 刊名 | bulletin of environmental contamination and toxicology
 |
| 出版日期 | 2007-07-01 |
| 卷号 | 79期号:1页码:66-70 |
| 关键词 | catalytic wet air oxidation Ru catalysts bubbling bed reactor eggshell catalyst coke-plant wastewater |
| 通讯作者 | 孙承林 |
| 英文摘要 | catalytic wet air of coke-plant wastewater was studied in a bubbling bed reactor. two types of supported ru-based catalysts, eggshell and uniform catalysts, were employed. compared with the results in the wet air oxidation of coke-plant wastewater, supported ru uniform catalysts showed high activity for chemical oxygen demand (cod) and ammonia/ammonium compounds (nh3-n) removal at temperature of 250 degrees c and pressure of 4.8 mpa, and it has been demonstrated that the catalytic activity of uniform catalyst depended strongly on the distribution of active sites of ru on catalyst. compared to the corresponding uniform catalysts with the same ru loading (0.25wt.% and 0.1wt.%, respectively), the eggshell catalysts showed higher activities for codcr removal and much higher activities for nh3-n degradation. the high activity of eggshell catalyst for treatment of coke-plant wastewater can be attributed to the higher density of active ru sites in the shell layer than that of the corresponding uniform catalyst with the same ru loading. it has been also evidenced that the active ru sites in the internal core of uniform catalyst have very little or no contribution to codcr and nh3-n removal in the total oxidation of coke-plant wastewater. |
| WOS标题词 | science & technology ; life sciences & biomedicine |
| 类目[WOS] | environmental sciences ; toxicology |
| 研究领域[WOS] | environmental sciences & ecology ; toxicology |
| 关键词[WOS] | organic-compounds ; removal ; phenol |
| 收录类别 | SCI |
| 原文出处 | false |
| 语种 | 英语 |
| WOS记录号 | WOS:000248910900015 |
| 公开日期 | 2010-11-30 |
| 源URL | [http://159.226.238.44/handle/321008/99149]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, Grp 902, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yang, M.,Sun, Y.,Xu, A. H.,et al. Catalytic wet air oxidation of coke-plant wastewater on ruthenium-based eggshell catalysts in a bubbling bed reactor[J]. bulletin of environmental contamination and toxicology,2007,79(1):66-70. |
| APA | Yang, M..,Sun, Y..,Xu, A. H..,Lu, X. Y..,Du, H. Z..,...&Li, C..(2007).Catalytic wet air oxidation of coke-plant wastewater on ruthenium-based eggshell catalysts in a bubbling bed reactor.bulletin of environmental contamination and toxicology,79(1),66-70. |
| MLA | Yang, M.,et al."Catalytic wet air oxidation of coke-plant wastewater on ruthenium-based eggshell catalysts in a bubbling bed reactor".bulletin of environmental contamination and toxicology 79.1(2007):66-70. |
入库方式： OAI收割
来源：大连化学物理研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。